A fascinating phase transition from one liquid state to another

A fascinating phase transition: From one liquid state to another
Time evolution of dielectric loss spectra during liquid-liquid transition of triphenyl phosphite at 214 K. The horizontal axis is the measurement frequency. The frequency of the peak shifts to lower frequencies with time, the dynamics of liuquid is drastic slowing down of with liquid-liquid transition. Credit: 2019 Hajime Tanaka, Institute of Industrial Science, The University of Tokyo

A team at the University of Tokyo has described in unprecedented detail the rare phenomenon of liquid-to-liquid phase transitions in a pure substance. By showing how a liquid made of just one type of molecule can switch between liquid and glassy states, this research may lead to a novel way to control the transport properties of a liquid.

Phase transitions include such phenomena as ice melting (solid to liquid), or steam coming from a teakettle (liquid to gas). However, the study of how one arrangement of changes into another reveals complex details about the strength of their interactions. In conventional , as with an iron bar melting into , added heat causes the atoms to vibrate so violently that they break free of their solid lattice arrangement and assume a liquid form. The team at the University of Tokyo studied a much rarer type of phase transition: from one to another. In this research, they found that even without changing , relatively free-flowing triphenyl phosphite could gradually vitrify into a glassy state in which the molecules remain disordered but are much less mobile. The different phases were identifiable experimentally based on how quickly the molecules could relax after being perturbed.

"Contrary to intuition, there is a growing body of experimental and theoretical evidence that even a single-component substance may have multiple liquid states," says lead author Hajime Tanaka. They found that the phase transition can occur in two very different ways. The first is called "nucleation and growth," a slow process that requires the emergence of one phase in the other overcoming a barrier to get started. The other type is spinodal decomposition, in which the transition can smoothly proceed without any barrier. The researchers also discovered a , above which only nucleated growth could occur, but below this temperature, spinodal decomposition was possible.

"From the viewpoint of practicality, triphenyl phosphite may be one of the best systems for studying liquid-to-liquid transitions, since the transformation takes place at and moderate temperatures," says first author Ken-ichiro Murata. "Phase transitions, particularly those that involve a change from a liquid to a glassy state, are often used in the manufacturing of polymers. This research may greatly enhance our ability to optimize and control these processes."

The study is published in PNAS.


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More information: Ken-ichiro Murata el al. Link between molecular mobility and order parameter during liquid–liquid transition of a molecular liquid.PNAS (2019). www.pnas.org/cgi/doi/10.1073/pnas.1822016116
Citation: A fascinating phase transition from one liquid state to another (2019, March 26) retrieved 19 May 2019 from https://phys.org/news/2019-03-fascinating-phase-transition-liquid-state.html
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