Figure 1. Giant thermopower of ionic thermoelectric (i-TE) materials. (A) i-TE materials of Gelatin-x KCl-m/n FeCN4-/3- (x is KCl and m/n are K4Fe(CN)6/K3Fe(CN)6 molar concentrations, respectively) in this work as Gelatin (x = 0 M, m/n = 0 M), Gelatin-FeCN4-/3- (x = 0 M, m/n = 0.42/0.25 M), Gelatin-KCl (x = 0.8 M, m/n = 0 M) and Gelatin-KCl-FeCN4-/3- (x = 0.8 M, m/n = 0.42/0.25 M, volume ratio of water to gelatin rv = 2.0 and 3.0). (B) Absolute thermopower of i-TE materials containing the thermodiffusion effect or the thermogalvanic effect. Credit: Southern University of Science and Technology

Ground-breaking research published in Science and led by Southern University of Science and Technology (SUSTech) has found that gelatin could be used to power devices in the future, using only the heat generated from the human body.

Associate Professor Weishu Liu (MSE, SUSTech) has led his research team, in collaboration with Professor Gang Chen at the Department of Mechanical Engineering, Massachusetts Institute of Technology (MIT), to develop a proof-of-concept wearable device powered by gelatin. The paper was published online in the high-impact academic journal, Science as First Release, under the title, "Giant thermopower of ionic gelatin near room temperature," on Thursday April 30, 2020

The majority of thermoelectric materials are inorganic semiconductors that require noble metals or processing technology. Researchers have focused on the exploring of new thermoelectric materials near , that utilize the Seebeck effect to convert thermal energy to electrical energy. The use of self-powered electronic thermoelectric devices requires the integration of thousands or even tens of thousands of tiny thermoelectric elements of 10—100 microns, or include a DC-DC voltage booster with a cost of the output power density.

Ahead of the voltage match challenge, Weishu Liu called for an exploration of "going beyond Seebeck" by considering use ions and electrical domain as an energy carrier, or other new mechanisms to solve this thermoelectric application challenge. These recommendations were made in his paper titled "New trends, strategies, and opportunities in thermoelectric materials: A perspective," published in Materials Today Physics in 2017.

Figure 2. Proof-of-concept of wearable i-TE device. (A) Tensile test of i-TE material. (B) Voltage generated from a proof-of-concept flexible i-TE wearable device with 25 unipolar elements (5 × 5 × 1.8 mm) in series worn on the back of human hand. (C) Power (line, −), voltage (dash line, –), output current (dash dot line, -∙-) curves by harvesting the real body heat. (D) Performance comparison in output voltage and power of the wearable device by using e-TE materials and quasi-solid state i-TE materials under a real human body wearing condition. N represented the number of the n/p-typed thermoelectric elements in the wearable devices. Credit: Southern University of Science and Technology

The paper published today in Science is a reflection of many years of hard work. The gelatin in question is a high-molecular substance that is found in bones. It is sought after by chefs in a wide range of cuisines while also being an essential raw material for several industrial applications.

The research team originally proposed that a quasi-solid ionic gel could achieve a giant thermoelectric potential effect by combining the effect of the diffused entropy of ions and the reaction entropy of the redox couple (chemical reduction-oxidation reaction). They achieved a thermopower of 17.0 mV K-1 in quasi-solid state ionic thermoelectric material, which is nearly two orders of magnitude higher than that of typical electronic thermoelectric

The research team then assembled twenty-five units to represent a proof-of-concept device. Each unit was assembled into a flexible wearable , using a human body for power. The researchers could achieve a voltage of up to 2.2 volts (V) and a maximum power output of 5 μW. While that seems small, it can drive the sensors of most Internet of Things (IoT) devices.

Weishu Liu said, "The experimental discovery of the giant thermoelectric effect brought us joy, and then many questions. Prof. Gang Chen provided us with the essential guidelines to answer each question one by one. It also allowed us to realize the truth about the joy of research: Never give up your exploring, as it is all about your dream. You need to keep searching till you get the truth, to find new knowledge."

More information: Cheng-Gong Han et al. Giant thermopower of ionic gelatin near room temperature, Science (2020). DOI: 10.1126/science.aaz5045

Journal information: Science

Provided by Southern University of Science and Technology