Supercharging silicon batteries

September 6, 2017
Members of the Nanoparticles by Design Unit besides the Cluster Beam Deposition machine used to manufacture the new silicon anode. Credit: Okinawa Institute of Science and Technology

As the world shifts towards renewable energy, moving on from fossil fuels, but at the same time relying on ever more energy-gobbling devices, there is a fast-growing need for larger high-performance batteries. Lithium-ion batteries (LIBs) power most of our portable electronics, but they are flammable and can even explode, as it happened to a recent model of smartphone. To prevent such accidents, the current solution is to encapsulate the anode – which is the negative (-) electrode of the battery, opposite to the cathode (+) - into a graphite frame, thus insulating the lithium ions. However, such casing is limited to a small scale to avoid physical collapse, therefore restraining the capacity - the amount of energy you can store - of the battery.

Looking for better materials, offers great advantages over carbon graphite for in terms of capacity. Six atoms of carbon are required to bind a single atom of lithium, but an atom of silicon can bind four atoms of lithium at the same time, multiplying the battery capacity by more than 10-fold. However, being able to capture that many lithium ions means that the volume of the anode swells by 300 percent to 400 percent, leading to fracturing and loss of structural integrity. To overcome this issue, OIST researchers have now reported in Advanced Science, the design of an anode built on nanostructured layers of silicon – not unlike a multi-layered cake – to preserve the advantages of silicon while preventing physical collapse.

This new battery is also aiming to improve power, which is the ability to charge and deliver energy over time.

"The goal in battery technology right now is to increase charging speed and power output," explained Dr. Marta Haro Remon, first author of the study. "While it is fine to charge your phone or your laptop over a long period of time, you would not wait by your electric car for three hours at the charging station."

Schematic representation of the Cluster Beam Deposition technique used to synthesize the silicon anode. Starting from a copper frame (in orange on the right), the anode is built layer by layer by alternatively depositing Silicon (top) and nanostructured tantalum metal (bottom) with great control. Credit: OIST Nanoparticles by Design Unit

And when it comes to providing energy, you would want your car to start off quickly at a traffic light or a stop sign, requiring a high spike in power, rather than slowly creeping forward. A well-thought design of a silicone-based anode might be a solution and answer these expectations.

The idea behind the new anode in the Nanoparticles by Design Unit at the Okinawa Institute of Science and Technology Graduate University is the ability to precisely control the synthesis and the corresponding physical structure of the nanoparticles. Layers of unstructured silicon films are deposited alternatively with tantalum metal nanoparticle scaffolds, resulting in the silicon being sandwiched in a tantalum frame.

"We used a technique called Cluster Beam Deposition," continued Dr. Haro. "The required materials are directly deposited on the surface with great control. This is a purely physical method, there are no need for chemicals, catalysts or other binders."

Supercharging silicon batteries
Schematic representation of a detail in the multi-layered anode. The porosity of the nanostructured Tantalum (in black) enables the formation of silicon channels (in blue) allowing lithium ions to travel faster within the battery. The rigidity of the tantalum scaffold also limits the expansion of the silicon and preserve structural integrity. Credit: OIST Nanoparticles by Design Unit

The outcome of this research, led by Prof. Sowwan at OIST, is an with higher power but restrained swelling, and excellent cyclability – the amount of cycles in which a battery can be charged and discharged before losing efficiency. By looking closer into the nanostructured layers of silicon, the scientists realized the silicon shows important porosity with a grain-like structure in which lithium ions could travel at higher speeds compared to unstructured, amorphous silicon, explaining the increase in power. At the same time the presence of silicon channels along the Ta nanoparticle scaffolds allows the lithium ions to diffuse in the entire structure. On the other hand, the tantalum metal casing, while restraining swelling and improving structural integrity, also limited the overall capacity – for now.

However, this design is currently only at the stage of proof-of-concept, opening the door to numerous opportunities to improve capacity along with the increased power.

"It is a very open synthesis approach, there are many parameters you can play around," commented Dr. Haro. "For example, we want to optimize the numbers of layers, their thickness, and replace tantalum metal with other materials."

With this technique paving the way, it might very well be that the solution for future batteries, forecast to be omnipresent in our lives, will be found in nanoparticles.

Explore further: Lithium-ion batteries will get more efficiency due to silicon, germanium, carbon nanowalls

More information: Marta Haro et al. Nanoscale Heterogeneity of Multilayered Si Anodes with Embedded Nanoparticle Scaffolds for Li-Ion Batteries, Advanced Science (2017). DOI: 10.1002/advs.201700180

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