This article has been reviewed according to Science X's editorial process and policies. Editors have highlighted the following attributes while ensuring the content's credibility:

fact-checked

peer-reviewed publication

trusted source

proofread

Combining extreme-ultraviolet light sources to resolve a quantum mechanical dissociation mechanism in oxygen molecules

Combining extreme-ultraviolet light sources to resolve a quantum mechanical dissociation mechanism in oxygen molecules
Overview of the measurement concept and absorption data. Credit: Science Advances (2023). DOI: 10.1126/sciadv.adk1482

For the first time, researchers have succeeded in selectively exciting a molecule using a combination of two extreme-ultraviolet light sources and causing the molecule to dissociate while tracking it over time. This is another step towards specific quantum mechanical control of chemical reactions, which could enable new, previously unknown reaction channels.

The interaction of light with matter, especially with molecules, plays an important role in many areas of nature, for example in such as photosynthesis. Technologies such as use this process as well.

On the Earth's surface, mainly light in the visible, ultraviolet or infrared regime plays a role here. Extreme-ultraviolet (XUV) light—radiation with significantly more energy than —is absorbed by the atmosphere and therefore does not reach the Earth's surface. However, this XUV radiation can be produced and used in the laboratory to enable a selective excitation of electrons in molecules.

While the in a molecule are held together by their outermost electrons in a kind of negatively charged cloud—they act as a sort of "chemical glue"—inner shell electrons are bound closer to an atomic nucleus and are therefore more localized in the molecule. It is precisely these electrons that can now be specifically excited with XUV radiation. This enables new chemical reaction processes that do not occur naturally on the Earth's surface.

A collaboration of researchers under the lead of the group of PD Dr. Christian Ott in the Department of Prof. Pfeifer at the Max-Planck-Institut für Kernphysik in Heidelberg, Germany, has now succeeded in combining two different XUV light sources for the first time, in order to temporally resolve a quantum mechanical dissociation mechanism in oxygen molecules.

The team's work is published in the journal Science Advances.

To achieve this, on the one hand, are generated with the process of high harmonic generation (HHG), in which is guided through a gas cell and thereby converted into XUV radiation—known, for example, from this year's Nobel Prize in Physics. On the other hand, a (FEL) is used, in which accelerated electrons emit XUV light. Both methods generate XUV pulses with a duration of femtoseconds, a millionth of a billionth of a second.

The decisive factor here is that the spectra of the two laser pulses are very different. "The HHG pulses have a very broad spectrum, which means they consist of light with many different frequencies—in the visible range this could be understood as different colors. The FEL pulses, on the other hand, are much more limited spectrally," explains Ph.D. student and first author of the study Alexander Magunia.

The FEL pulses are generated at the free-electron laser in Hamburg (FLASH@DESY) and used to excite the electrons of the oxygen molecule into a specific state. It is known that this state then causes the molecule to dissociate via two different channels. However, it has been unclear until now how fast this happens. This is because the atoms in the oxygen molecule have to go through a "quantum tunneling" process, which makes exact theoretical descriptions more difficult.

By adding the second HHG pulse with an adjustable to the first exciting FEL , this molecular dissociation can now be recorded experimentally—like in a fast photo series. The HHG pulses make it possible to "photograph" all the resulting fragments at once through their spectral absorption fingerprints—a decisive step.

The larger the time delay between the two pulses, the more molecules have already decayed. This increase in fragments ultimately allows researchers to determine the duration of the process and the respective rates for the two decay channels.

The possibility of initiating targeted electronic or molecular processes with FEL pulses and independently reading out a wide range of quantum-mechanical state information about the molecule or its individual fragments with the broadband HHG spectra will hopefully make it possible to record, understand and ultimately control more complex chemical reactions with light in the future.

More information: Alexander Magunia et al, Time-resolving state-specific molecular dissociation with XUV broadband absorption spectroscopy, Science Advances (2023). DOI: 10.1126/sciadv.adk1482

Journal information: Science Advances

Provided by Max Planck Society

Citation: Combining extreme-ultraviolet light sources to resolve a quantum mechanical dissociation mechanism in oxygen molecules (2023, November 22) retrieved 23 February 2024 from https://phys.org/news/2023-11-combining-extreme-ultraviolet-sources-quantum-mechanical.html
This document is subject to copyright. Apart from any fair dealing for the purpose of private study or research, no part may be reproduced without the written permission. The content is provided for information purposes only.

Explore further

Nobel prize in physics awarded for work unveiling the secrets of electrons

238 shares

Feedback to editors