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Treatment creates steel alloys with superior strength and plasticity

Treatment creates steel alloys with superior strength and plasticity
Quasi–in situ EBSD analyses on the G-T91 under uniaxial tensile tests.IPFs and GROD maps from the (A to F) CG and (H to M) FG regions of the G-T91 at 0, 3, and 6% plastic strain. The IPFs taken along the SD display the grain morphology and crystal orientation evolution with the tensile strain in the two regions. Locally magnified GROD maps indicate the corresponding intragranular strain distribution. (G and N) Representative line scans were drawn in grain interior to quantify the point-to-origin misorientation variation at 0, 3, and 6% tensile strain in the two regions. Credit: Science Advances (2023). DOI: 10.1126/sciadv.add9780

A new treatment tested on a high-quality steel alloy produces extraordinary strength and plasticity, two traits that must typically be balanced rather than combined. Ultra-fine metal grains that the treatment produced in the outermost layer of steel appear to stretch, rotate and then elongate under strain, conferring super-plasticity in a way that Purdue University researchers cannot fully explain.

The researchers treated T-91, a modified steel alloy that is used in nuclear and petrochemical applications, but said the treatment could be used in other places where strong, ductile steel would be beneficial, such as car axles, suspension cables and other structural components. The research, which was conducted in collaboration with Sandia National Laboratories and has been patented, appeared in Science Advances.

More intriguing even than the immediate result of a stronger, more plastic variant of T-91 are observations made at Sandia showing characteristics of what the team is calling a "nanolaminate" of ultra-fine grains the treatment created in a region extending from the surface to a depth of about 200 microns.

Microscopy images show an unexpected deformation of the treated steel—dubbed G-T91 (or gradient T91) —as it is subjected to increasing stress, said Xinghang Zhang, lead author and a professor in the School of Materials Engineering at Purdue.

"This is a complex process, and the has not seen this phenomenon before," Zhang said. "By definition, the G-T91 is showing super-plasticity, but the exact mechanism that allows this is unclear."

Metals like steel may look monolithic to the naked eye, but when greatly magnified, a metal bar reveals itself to be a conglomeration of individual crystals called grains. When a metal is subjected to strain, the grains are able deform in such a way that the metallic structure is maintained without rupturing, allowing the metal to stretch and bend. Larger grains can accommodate greater strain than smaller grains, the foundation to a fixed trade-off between large-grain deformable metals and small-grain strong metals.

In the Science Advances paper, lead author Zhongxia Shang, a former graduate student in Zhang's lab, used compressive and shear stresses to break large grains at the surface of a T-91 sample into smaller grains. A cross-section of the sample shows that grain sizes increase from the surface, where the smallest ultra-fine grains are less than 100 nanometers in size, into the center of the material, where grains are 10 to 100 times larger.

The modified G-T91 sample had a yield strength of about 700 megapascals, a unit of tension stress, and withstood a uniform strain of about 10%, a significant improvement over the combined strength and plasticity that can be reached with standard T-91.

"This is the beauty of the structure; the center is soft so it can sustain plasticity but, by introducing the nanolaminate, the surface has become much harder," said Shang, now a research staff scientist at Purdue's Birck Nanotechnology Center. "If you then create this gradient, with the large grains in the center and nanograins in the surface, they deform synergistically. The large grains take care of the stretching, and the small grains accommodate the stress. And now you can make a material that has a combination of strength and ductility."

While the research team had hypothesized that the gradient nanostructured G-T91 would perform better than standard T-91, scanning electron taken at intervals during the tension testing reveal a mystery.

Electron backscattered diffraction images taken at a at Sandia show how grains in the nanolaminate of the G-T91 change at increasing intervals of true strain, a measure of plasticity, from 0% to 120%. At the beginning of the process, the grains are vertical, with a shape the team describes as lenticular. But as strain increases, they appear to stretch into a more globular shape, then rotate, and finally, elongate horizontally.

Zhang said the images show the interface between the grains—called the grain boundary—moving, allowing the grains to stretch and rotate and enabling the steel itself to deform plastically. The team now plans to investigate the rules governing this movement in the grain boundaries, which could make it possible to understand the intriguing deformation behavior of gradient materials.

"If we know how they move and why they move, maybe we can find a better way to arrange the . We don't know how to do it yet, but it's opened a very interesting potential," Zhang said.

More information: Zhongxia Shang et al, Gradient nanostructured steel with superior tensile plasticity, Science Advances (2023). DOI: 10.1126/sciadv.add9780

Journal information: Science Advances

Provided by Purdue University

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