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Creating a new, sustainable plastic using physics

Creating a new, sustainable plastic using physics
Polyelectrolytes with varying degrees of intrinsic screening form compleximers upon mixing in solution.Four investigated polyelectrolytes consist of a polystyrene backbone with ionic liquid-inspired side chains. The alkyl and fluoroalkyl tail lengths are varied to modify the interaction strength. (A) Non-screened (NS) compleximer has relatively accessible ionic groups, allowing for strong ionic bonding, similar to traditional PECs. (B) Half-screened (HS) compleximer is made with a highly screened polycation, decreasing the strength of the ionic interactions in the complex. (C) Screened (S) compleximer contains screening tails in both the polycation and the polyanion, leading to the weakest binding capability. (D) Schematic illustration of complexation. Compleximers are produced by dissolution of a respective polycation or polyanion and subsequent simultaneous mixing, which leads to the precipitation of a solid complex. These are washed with water until the conductivity reaches equilibrium close to the conductivity of MilliQ water, removing all free counterions from the complex. The final compleximer is obtained as a dry powder. nr., number. Credit: Science Advances (2024). DOI: 10.1126/sciadv.adi3606

For the past three years, Ph.D. candidate Sophie van Lange has been dedicated to one clear goal: producing plastic that is both hard and sustainable. The plastics we use today are either recyclable or strong and hard—not both. Van Lange stepped away from traditional chemical approaches to produce plastic and developed a completely new method to create durable and reusable plastic in a completely new way. The trick? Physical forces.

The process begins with a seemingly simple setup: a yellow powder in one dish and a white powder in another. By dissolving and combining these two solutions, and subjecting them to heat and pressure in a hot press, Van Lange transforms these substances into a rectangular piece of measuring two by half a centimeter within two weeks.

Under normal conditions, the resulting plastic is sturdy and hard but becomes reformable when heated. She refers to these innovative plastics as "compleximers." Van Lange and her colleagues report on this in Science Advances.

Sustainable plastic processing

Plastics are ubiquitous in our daily lives, serving as packaging for peppers and cucumbers in the supermarket or as packaging for new toys. "But plastic is also incorporated in the shoes on my feet and the glasses on my nose," says Van Lange, pointing to her pink frames. Yet we rarely consider what happens to these after the shoes break or when you need new glasses.

"You can take old items to a recycling point, but hardly anyone knows exactly what happens to them afterward," says the young researcher. Consider a shoe sole, which is also a type of plastic. After use, we cannot do anything with it except burn or grind it. Other plastics, like the bag around a pepper or the layer in a milk carton, can be recycled.

"How great would it be if we could process all plastics sustainably," Van Lange says. She is driven by her love for sustainable materials and works on this innovative plastic in the Physical Chemistry and Soft Matter chair group. "I think are really cool," she says.

"On a molecular scale, plastics consist of long chains," explains Van Lange. In traditional hard plastics, these chains are connected by chemical cross-links for strength. However, these cross-links are so robust that recycling becomes nearly impossible. That is why Van Lange redesigned these without chemical cross-links, this time utilizing adjustable physical forces.

Force of attraction

"Half of the chains that make up our plastic are positively charged," Van Lange explains.

"The other half is negatively charged." When you bring them into contact with each other correctly, they attract each other, just like two magnets. This keeps the chains together without the need for chemical cross-links. When heated, the attraction between the parts weakens, allowing the entire material to reshape. "This enables the plastic to be reused or, for example, to repair a hole or other damage in the plastic with heat," says Van Lange.

So far, the Ph.D. candidate has produced approximately three grams of the new plastic. "It took a while before my colleagues and I actually had the desired plastic," she says. It all boiled down to attraction: in nature, positive and negative particles strongly attract each other. This makes materials brittle and nearly impossible to deform when heated. "The innovation lies in sufficiently weakening that charge," says Van Lange.

She achieved that with a kind of "molecular umbrella" that partially shields the positive and in the plastic. "That is how we achieved the perfect attraction force and, consequently, plastic that is easily deformable when heated," says the Ph.D. candidate. Moreover, these umbrellas are water-repellent, ensuring the plastic remains robust when exposed to water. A shoe sole made from the new plastic stays sturdy when stepping into a puddle. "Charged material is almost always sensitive to water, so achieving this is very special," adds Van Lange.

More flexibility

The new plastic is not yet entirely ready yet. For example, the material is not yet flexible enough, according to Van Lange say, "We demonstrate that the concept works, but now we need to find a way to give it more rubber-like properties." The researcher hopes to achieve this by reducing the charge in compleximers, perhaps by adjusting the building blocks of the chains that make up the plastic.

"An alternative could be to enlarge the molecular umbrellas," says Van Lange. She also considers altering the type of chains. "We currently use polystyrene, a stiff molecule," explains the Ph.D. candidate. "If we replace it with a more flexible variant, we might already get a more bendable plastic."

Although the plastic is not yet ready for the market, the Ph.D. candidate hopes that her work will inspire other researchers. Her research demonstrates that thinking outside the box can lead to entirely new materials. "I want to motivate other scientists to look at materials differently and use them in unconventional ways," concludes Van Lange.

More information: Sophie G. M. van Lange et al, Moderated ionic bonding for water-free recyclable polyelectrolyte complex materials, Science Advances (2024). DOI: 10.1126/sciadv.adi3606

Journal information: Science Advances

Citation: Creating a new, sustainable plastic using physics (2024, January 19) retrieved 20 April 2024 from
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