New method makes generic polymers luminescent

New method makes generic polymers luminescent
Ball-milling the mixture of polystyrene and pre-fluorescent radical reactants yielded luminescent polymers. Photos show the mixture before (left) and after (right) the reaction, under UV light. Credit: Koji Kubota et al., Angewandte Chemie International Edition. May 14, 2021

Researchers from Hokkaido University have successfully developed a new method to give luminescent properties to generic polymers, such as polystyrene and polyethylene. The technique, which was published in the journal Angewandte Chemie International Edition, makes it possible to easily prepare luminescent polymers without using complicated organic synthetic methods.

"Luminescent polymers are widely used in modern society, in applications such as organic lasers, , sensors and bioimaging, but their preparation often requires multiple chemical synthesis steps, which are both time and labor intensive," explains Professor Hajime Ito, one of the authors of the study and Vice Director of the Institute for Chemical Reaction Design and Discovery (WPI-ICReDD) at Hokkaido University.

To overcome this problem, the research team investigated whether luminescent polymers could be prepared using mechanical force as opposed to sophisticated chemical synthesis.

"It is well known that mechanically stimulating polymers, for example by grinding or crushing them, generates reactive species called ," says Associate Professor Koji Kubota from Hokkaido University, a paper co-author. "Inspired by this phenomenon, as well as our previous research into -induced luminescence and reactions, we wanted to investigate whether we could find a simpler method for preparing functional luminescent materials."

New method makes generic polymers luminescent
Ball-milling generic polymers with prefluorescent radical reactants yielded luminescent polymers. Credit: Koji Kubota et al., Angewandte Chemie International Edition. May 14, 2021

In this study, the researchers placed the polymer and pre-fluorescent radical reactants together in a ball milling jar containing stainless steel balls. The jar was then shaken, causing the balls to grind the solid compounds and initiate a reaction. During this process, the in the were cleaved and the pre-fluorescent molecules were inserted into the , gaining significantly higher emission intensity. The researchers successfully applied this method to polystyrene, polyethylene, polyphenylene sulfide, polysulfone, and other generic polymers.

"With further development, the method could potentially be adapted to introduce other functions to generic polymers," says Hokkaido University Assistant Professor Mingoo Jin.

"In the future, we hope to use this method to develop novel sensing and recording materials that change color in response to mechanical stimuli," Hajime Ito added.

This could pave the way for "smart" materials for a wide range of applications, such as bioimaging reagents and pressure-sensitive sensors.

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More information: Koji Kubota et al, Introduction of a Luminophore into Generic Polymers via Mechanoradical Coupling with a Prefluorescent Reagent, Angewandte Chemie International Edition (2021). DOI: 10.1002/anie.202105381
Citation: New method makes generic polymers luminescent (2021, June 11) retrieved 6 July 2022 from
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