Scientists propose novel electrode for efficient artificial synthesis of ammonia

Scientists propose novel electrode for efficient artificial synthesis of ammonia
Illustration of the PEC NRR process on BP electrode. Credit: WANG Jiahong

Ammonia (NH3) is an important chemical in the industry and agriculture as well as an emerging energy carrier with large hydrogen content.

As an alternative to the high energy-intensive Haber-Bosch ammonia , photoelectrochemical (PEC) technique has been proposed to produce ammonia from N2 and H2O at ambient atmosphere. However, efficient and noble metal-free materials are still the key to PEC synthesis of ammonia.

A research team led by Dr. WANG Jiahong and Prof. YU Xuefeng from the Shenzhen Institutes of Advanced Technology (SIAT) of the Chinese Academy of Sciences proposed a (BP) electrode for efficient artificial synthesis of ammonia.

The electrode was fabricated by layer-by-layer assembly of BP nanosheets on an (ITO) substrate as the metal-free two-dimensional catalyst for the photoelectrochemical (PEC) nitrogen reduction reaction (NRR).

The study, titled "Photoelectrochemical Synthesis of Ammonia with Black Phosphorus," was published in Advanced Functional Materials on April 20.

In this study, the BP electrode exhibited highly efficient PEC NRR activity with the ammonia yield rate of 102.4 μg·h-1 mgcat.-1, the Faradaic efficiency of 23.3% at -0.4 V and good long-term stability, which was the best among nonmetal catalysts for synthesis of ammonia by photocatalysis and electrocatalysis.

Moreover, the desorption favorable surface, raised flat band, external electric field, and consumed holes improved the ammonia productivity synergistically.

"BP has many features that are suitable for synthesis of ," said Dr. WANG Jiahong. "It's a direct bandgap semiconductor with high carrier mobility as well as light absorption spanning a wide range. The weak hydrogen absorption on bare BP also can suppress the competing hydrogen evolution reaction. The NRR catalyst library would be expanded by the introduction of p-type two-dimensional material."

More information: Danni Liu et al. Photoelectrochemical Synthesis of Ammonia with Black Phosphorus, Advanced Functional Materials (2020). DOI: 10.1002/adfm.202002731

Journal information: Advanced Functional Materials

Citation: Scientists propose novel electrode for efficient artificial synthesis of ammonia (2020, May 27) retrieved 23 February 2024 from
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