Dynamic compression provides new insight into understanding and predicting crystal growth

Dynamic compression provides new insight into understanding and predicting crystal growth
This schematic illustration depicts the transition of ice growth by dynamic compression using the advanced dynamic diamond anvil cell, which enhances interface structure and leads fast interface kinetics of water-ice interface, initiating two-dimensional shock growth even near equilibrium melting pressure. Credit: Yong-Jae Kim and James Wickboldt/LLNL

Crystal growth is a crucial issue for fundamental science and wide applications. The growth morphology and speed are generally determined by an interplay between macroscopic thermodynamic driving forces and the microscopic kinetic process at crystal-liquid interface.

While crystal is well understood at near-equilibrium growth conditions, the growth transition with diverse growth morphologies are poorly understood under nonequilibrium growth conditions (e.g. ).

A study recently published in the Proceedings of the National Academy of Sciences (PNAS) provides a new insight of crystal growth under dynamic compression using an advanced dynamic diamond anvil cell (dDAC) technique, which bridges the unknown behaviors of crystal growth between static and dynamic pressure conditions. The work was conducted by a collaborative research team from the Korea Research Institute of Standards and Science (KRISS), University of Science and Technology (UST) in South Korea and Japan's National Institute of Advanced Industrial Science and Technology (AIST). Co-lead author Yong-Jae Kim, a physicist at Lawrence Livermore National Laboratory, conducted the research as a postdoctoral researcher at KRISS.

"Our study makes a step forward in better understanding and predicting crystal growth in the real world, from diverse snowflakes to planet interiors at extreme conditions," Kim said.

The team revealed the origin of pressure-induced shock growth of single ice showing reduced dimensionality by controlling local growth conditions using the advanced dDAC. The local structure at the water-ice interface is enhanced by fast compression, facilitating fast interface kinetics and thus two-dimensional (2-D) shock growth initiation, even near equilibrium melting pressure.

With the advanced dDAC, the team simultaneously measured morphology evolution, microstructures (with Raman spectroscopy or X-ray diffraction) and surrounding growth conditions (such as pressure and cell volume) during crystal growth. They also performed for more elaborate microscopic understanding of the physical situation at the water-ice interface.

"Generally, rapid crystal growth results from the fast growth of crystal corners under a large driving force, finally leading to the formation of a dendritic morphology. Contrary to the general expectation, fast compression initiated the 2-D shock growth from the edges of the initial 3-D crystal with at least one order higher growth speed, rather than from its corners, although the measured pressure of the entire system is almost close to the melting pressure of ice (i.e. small driving force)," Kim said. "This implies the fast compression causes effectively large overpressure at the crystal edges. Such a large effective driving force leads to a similar interface structure as bulk crystals along the shock growth plane, finally facilitating fast interface kinetics causing 2-D shock growth."

Looking ahead, Kim plans to expand on this research by using laser-driven shock compression to explore the kinetics of and phase transitions at even faster timescales, with applications to a better understanding of the interior structure and evolution of icy planets like Uranus and Neptune.


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More information: Yong-Jae Kim et al. Shock growth of ice crystal near equilibrium melting pressure under dynamic compression, Proceedings of the National Academy of Sciences (2019). DOI: 10.1073/pnas.1818122116
Citation: Dynamic compression provides new insight into understanding and predicting crystal growth (2019, June 5) retrieved 16 June 2019 from https://phys.org/news/2019-06-dynamic-compression-insight-crystal-growth.html
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