New catalyst material produces abundant cheap hydrogen

November 29, 2018, Queensland University of Technology
Credit: CC0 Public Domain

QUT chemistry researchers have discovered cheaper and more efficient materials for producing hydrogen for the storage of renewable energy that could replace current water-splitting catalysts.

Professor Anthony O'Mullane said the potential for the chemical storage of renewable energy in the form of hydrogen was being investigated around the world.

"The Australian Government is interested in developing a hydrogen export industry to export our abundant renewable energy," said Professor O'Mullane from QUT's Science and Engineering Faculty.

"In principle, hydrogen offers a way to store at a scale that is required to make the rollout of large-scale solar and wind farms as well as the export of green energy viable.

"However, current methods that use carbon sources to produce hydrogen emit carbon dioxide, a greenhouse gas that mitigates the benefits of using renewable energy from the sun and wind.

"Electrochemical splitting driven by electricity sourced from renewable technology has been identified as one of the most sustainable methods of producing high-purity hydrogen."

Professor O'Mullane said the new composite material he and Ph.D. student Ummul Sultana had developed enabled electrochemical water splitting into hydrogen and oxygen using cheap and readily available elements as catalysts.

Credit: Queensland University of Technology
"Traditionally, catalysts for splitting water involve expensive precious metals such as iridium oxide, ruthenium oxide and platinum," he said.

"An additional problem has been stability, especially for the oxygen evolution part of the process.

"What we have found is that we can use two earth-abundant cheaper alternatives—cobalt and nickel oxide with only a fraction of gold nanoparticles – to create a stable bi-functional to split water and produce hydrogen without emissions.

"From an industry point of view, it makes a lot of sense to use one catalyst material instead of two different catalysts to produce hydrogen from water."

Professor O'Mullane said the stored hydrogen could then be used in fuel cells.

"Fuel cells are a mature technology, already being rolled out in many makes of vehicle. They use hydrogen and oxygen as fuels to generate electricity – essentially the opposite of water splitting.

"With a lot of cheaply 'made' we can feed -generated electricity back into the grid when required during peak demand or power our transportation system and the only thing emitted is water."

"Gold Doping in a Layered Co-Ni Hydroxide System via Galvanic Replacement for Overall Electrochemical" was published in Advanced Functional Materials.

Explore further: Plastic 'leaves' turn water into fuel

More information: Ummul K. Sultana et al. Water Splitting: Gold Doping in a Layered Co-Ni Hydroxide System via Galvanic Replacement for Overall Electrochemical Water Splitting (Adv. Funct. Mater. 43/2018), Advanced Functional Materials (2018). DOI: 10.1002/adfm.201870306

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4.5 / 5 (4) Nov 29, 2018
This is the first article that offers a viable use for H2 produced by intermittent renewables. It is much easier to build a containment vessel for a stationary power plant than to contain and distribute H2 for transportation purposes. Converting it to a liquid fuel is possible but energy intensive. Hydrides might be a solution but the economics have not been tested yet.
1 / 5 (4) Nov 30, 2018
This article ignores that fact that the hydrogen-electricity conversion is far from efficient. Far cheaper solution is using gravity to lift heavy objects.
5 / 5 (2) Dec 01, 2018
This all sounds lovely, but it's a long way from commercialization. How much does it cost to make this compared to current electrolyzer systems? How long does the catalyst last?

H2 is the devil to handle - diffuses through polymers, dissociates and tunnels through metals, and burns nicely. The best long term storage and transport method might be ammonia synthesis, but there are hazards to handling this caustic substance at the cryogenic temperatures needed to liquify it. Any step forward is a good one, given the climate troubles we face.
not rated yet Dec 04, 2018
Lol as early as 2010, I had created a plasma out of water to cheaply produce hydrogen
5 / 5 (3) Dec 31, 2018
Passing water vapour though a superconducting nano filter
raises the possibility of splitting oxygen
oxygen is paramagnetic, attracted to intense magnetic fields
burning the oxygen and hydrogen
feeding the hot water vapour back through the nano superconducting magnetic filters
reducing the amount of water fuel to be carried
this Aussie Water Engine
these Aussies have been tantalising the world with
will be realised
there is just one fly in the ointment
there are no room temperature superconductors as yet
Well not one that will takes this Aussie heat wave

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