Team develops new method to create the next fuel-efficient renewable energy

April 19, 2017, University of Southern California
USC scientists have found a way to tap hydrogen fuel from methanol without producing concurrent carbon. Credit: via G. K. Surya Prakash

Scientists have long struggled with generating and storing hydrogen, the kind that might one day provide the backbone for renewable energy fuel cells that make our cars move, warm our houses and help produce food, in a way that also won't hasten climate change or otherwise harm the environment.

In research published earlier this year in the Journal of the American Chemical Society, chemists at the USC Loker Hydrocarbon Research Institute outlined a carbon-neutral method for doing just that, with a little help from the simplest alcohol known to man: .

Senior author G. K. Surya Prakash, 1994 Nobel Prize in Chemistry winner Olah in his last major paper and their team at the USC Dornsife College of Letters, Arts and Sciences devised a way to produce and store hydrogen from methanol, without concurrent production of either carbon monoxide or carbon dioxide, by trapping it in organic derivatives of ammonia called amines.

The well-known steam reforming process usually used to extract hydrogen from methanol, called the methanol reformer, traditionally produces and carbon dioxide as part of this extraction process. Carbon dioxide is a greenhouse gas that causes global warming and ocean acidification.

The research demonstrates just one more way carbon has been freed from the cycle of creating and storing fuels via methanol, supporting Olah and Prakash's long-standing vision of a completely renewable "methanol economy."

Reducing reliance on carbon-emitting fossil fuels

"The Methanol Economy" is a concept that the Olah-Prakash team first began refining in the mid-1990s, right after the time Olah became USC's first Nobel laureate for his contributions to carbocations, the name that Olah himself coined for ions that have a positively charged carbon atom.

According to Olah and Prakash, the goal of a methanol-based economy would be to develop renewable sources of energy, led by methanol, that could mitigate the problem of climate change caused by carbon emissions, as well as the U.S. dependence on other countries for energy, particularly oil.

The need to offset crude oil consumption has only grown in the intervening decades since Olah and Prakash began their research. At that time, global consumption of oil was around 70 million barrels; that number is expected to be about 100 million as early as next year.

Countries like China have already begun the transition away from petroleum. At the beginning of the century, methanol use there was negligible but now accounts for more than 500,000 barrels each day, though much of it is coal-based, which can create its own problematic carbon runoff.

The research of Prakash, Olah and their team has been focused on finding a way to extract hydrogen fuel from methanol in ways that are not only carbon-neutral, but can even be -positive.

The roots of a carbon-free future

Methanol, sometimes called "wood alcohol," is the simplest alcohol that can be produced, requiring only water, and energy.

While methanol stores half the energy of traditional petroleum-based gasoline, the light that burns half as bright also burns more cleanly, with no soot, particulates or other residue. According to the Environmental Protection Agency, the combustion of methanol also generally produces less deleterious greenhouse gases in the form of nitrogen oxides.

Methanol quickly biodegrades. It has traditionally been produced from natural gas and can be corrosive to older automobile tubing and casing, though much less so to newer generations of automobiles. Methanol is a more efficient fuel to replace gasoline or diesel, but it provides fewer miles to the gallon because of its lower energy density.

Methanol has also long been prized by race car drivers for its higher octane on shorter tracks and because it produces clearer smoke, preventing pileups. Also, unlike typical petroleum-based gasoline, water is effective in fighting methanol-based fires, though those clean-burning fires often appear invisible in daylight. However, additives can also easily be added to methanol to increase visibility.

Methanol is also already employed in the raw chemical production of all petroleum-based chemicals and products.

In a testament to its elegance, simplicity and ubiquity, methanol naturally occurs in small amounts in the Earth's atmosphere, and there are even huge clouds of it floating in the star-forming regions of space. Olah, Prakash and colleagues published research last year examining the differences between the formation of methanol both terrestrially and extraterrestrially.

Prakash, who worked with Olah for more than 40 years, said "Olah was a giant of a chemist and a great visionary who had a prophetic approach to solve tough problems. He had remarkable memory and was quite intuitive. He was very well-read, he knew history and philosophy and appreciated music and the arts. He was a voracious reader. He can be described as a Renaissance man."

Explore further: Carbon dioxide captured from air can be directly converted into methanol fuel

More information: Jotheeswari Kothandaraman et al, Efficient Reversible Hydrogen Carrier System Based on Amine Reforming of Methanol, Journal of the American Chemical Society (2017). DOI: 10.1021/jacs.6b11637

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2.6 / 5 (5) Apr 19, 2017
"global consumption of oil was around 70 million barrels; that number is expected to be about 100 million as early as next year.

Countries like China have already begun the transition away from petroleum."

The USA is transitioning away too. 2010 USA petroleum consumption was 36 KQuads; in 2016 it was 35.9. Overall USA energy consumption fell from 98 KQuads to 97.3, even as activity and output have increased a lot (6 years after the depths of the recession), that transition is through efficiency.

Transitioning away from coal even more: down from 21 KQuads to 14.2 (7 years ago we used almost 50% more).

Nukes are up only 0.02 KQuads (0.2%), while natgas is up 3.5 KQuads from 25 (+14%). Sustainable solar/hydro/wind/geothermal/biomass are up a combined 2.23 KQuads, a 22.6% increase, even as overall energy demand shrinks.

China gets the name drop, but the USA is competing well.
5 / 5 (2) Apr 20, 2017
@Emcee; Ok, but how will that go with the policies of the new administration?
1 / 5 (6) Apr 20, 2017
Why do conservatives fear the future?

Is it because they cannot control it?
Apr 20, 2017
This comment has been removed by a moderator.
1 / 5 (3) Apr 20, 2017
The actual policies of the Trump administration are so far largely unknown. Even less known is its competence in implementing any policy.

The US energy system is a huge, highly ramified system that changes only slowly and in response to many independent stimuli. It has changed over the past decade, especially coming out of the recession, especially in its direction. That shows a lot of longterm stimuli changing it.

The Trump administration has a lot of power to screw up America, but it's uncertain how good it is at being bad. Most of its available tools are deregulation, which likely favors more energy efficiency and less competitive coal, gas and nukes. Just causing chaos, which does seem to be its specialty, favors domestic renewables. A solar trade war with China could just give US production a chance.

With so much political uncertainty it's unknowable, but the US energy trend to date is largely mainstream industry now.

how will

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