This article has been reviewed according to Science X's editorial process and policies. Editors have highlighted the following attributes while ensuring the content's credibility:

fact-checked

peer-reviewed publication

trusted source

proofread

New class of 2D material displays stable charge density wave at room temperature

New class of 2D material displays stable charge density wave at room temperature
Atoms of a tantalum disulfide (TaS2) crystal with a 2D endotaxial layer in the center. The pink cloud represents the charge density wave, a clumped pattern of electrons, surrounding the 2D layer. Credit: Hovden Laboratory

Quantum materials have generated considerable interest for computing applications in the past several decades, but non-trivial quantum properties—like superconductivity or magnetic spin—remain in fragile states.

"When designing quantum materials, the game is always a fight against disorder," said Robert Hovden, an associate professor of materials science and engineering at the University of Michigan.

Heat is the most common form of disorder that disrupts quantum properties. Quantum materials often only exhibit exotic phenomena at very low temperatures when the atom nearly stops vibrating, allowing the surrounding electrons to interact with one another and rearrange themselves in unexpected ways. This is why quantum computers are currently being developed in baths of liquid helium at −269 °C, or around -450 F. That's just a few degrees above zero Kelvin (-273.15 °C).

Materials can also lose quantum properties when exfoliated from 3D down to a 2D single layer of atoms, thinness of particular interest for developing nanoscale devices.

Now, a University of Michigan-led research team has developed a new way to induce and stabilize an exotic quantum phenomenon called a charge density wave at . They've essentially identified a new class of 2D materials. The results are published in Nature Communications.

"This is the first observation of a charge density wave that's ordered and in two dimensions. We were shocked that not only does it have a charge density wave in two dimensions, but the charge density wave is greatly enhanced," said Hovden.

Rather than the typical approach of exfoliating and peeling off individual atomic layers to make a 2D material, the researchers grew the 2D material inside of another matrix. They dubbed the new class of materials "endotaxial" from the Greek roots "endo", meaning within, and "taxis", meaning in an ordered manner.

The researchers worked with a metallic crystal, tantalum disulfide (TaS2), which, like any crystal, has atoms ordered in a pattern like neatly arranged ping pong balls in all directions. They observed that as the material grew, the electrons of the sandwiched 2D TaS2 crystal layer spontaneously clumped together to form their own crystal, known as a charge crystal or a charge density wave—a repeating pattern in the distribution of electrons in a solid material.

New class of 2D material displays stable charge density wave at room temperature
Long-range ordered incommensurate charge density waves. a Schematic representation of ordered IC-CDW. The CDW is two-dimensional with little disorder. b Ordered IC-CDW illustrated as a crystalline charge-density lattice. Here, white spots represent charge centers. Inset) Fourier transform of the charge lattice shows well-defined peaks. c Associated periodic lattice distortions (PLDs) move tantalum nuclei (black spots) along the charge density gradient. Inset) Simulated diffraction shows sharp superlattice peaks decorating Bragg peaks. d Schematic representation of ordered IC-CDW in endotaxial polytype heterostructure. Mono- or few layers of endotaxially protected Oc-TaS2 hosts 2D ordered IC-CDWs. e Schematic representation of hexatic IC-CDW. The CDW phase is quasi-2D with non-trivial interlayer interactions, and hexatically disordered. f Charge density distribution is comparable to hexatically disordered crystal lattice. Inset) Structure factor reveals azimuthally diffused peaks—characteristics of hexatic phases. g Associated lattice distortion of IC-CDW with (inset) Fourier transform showing azimuthally blurred superlattice peaks while maintaining sharp Bragg peaks. h Schematic representation of hexatic IC-CDW in bulk 1T-TaS2 where every layer hosts disordered IC-CDW. Credit: Nature Communications (2024). DOI: 10.1038/s41467-024-45711-3

As the electrons clump and crystallize, their movement is restricted, and the metal no longer conducts electricity well. Without changing the chemistry of the material, the charge crystal formation has converted the material from a conductor to an insulator. This exotic quantum phenomenon could prove useful as a transistor in either classical or quantum computing, acting as a gate to control voltage flow.

"This opens up the idea that endotaxial synthesis could be an important strategy to stabilize fragile quantum states at normal temperature ranges that we exist in," said Suk Hyun Sung, first author of the paper and a University of Michigan doctoral graduate and current postdoc at the Rowland Institute at Harvard University.

With a charge crystal stable at room temperature in hand, the researchers decided to heat it up to observe changes.

"It's ordered at unexpectedly high temperatures. Not only at room temperature but if you heat it up past the boiling point of water, it still has a charge density wave," said Hovden.

The researchers eventually watched the charge crystal melt away while the material remained solid, removing the .

Experiments like this advance our basic understanding of quantum materials, which is essential as researchers work to harness exotic quantum phenomena for engineering solutions.

"Quantum materials are going to disrupt both classical and quantum computing," said Hovden.

Both fields are stuck, says Hovden. Classical computing has exhausted what silicon can do and can currently only operate at extremely low temperatures. They need quantum materials to move forward.

For now, this research sets the groundwork for discovering new using the endotaxial synthesis and offers promise for stabilizing quantum properties at more practical temperatures.

More information: Suk Hyun Sung et al, Endotaxial stabilization of 2D charge density waves with long-range order, Nature Communications (2024). DOI: 10.1038/s41467-024-45711-3

Journal information: Nature Communications

Citation: New class of 2D material displays stable charge density wave at room temperature (2024, March 1) retrieved 15 April 2024 from https://phys.org/news/2024-03-class-2d-material-displays-stable.html
This document is subject to copyright. Apart from any fair dealing for the purpose of private study or research, no part may be reproduced without the written permission. The content is provided for information purposes only.

Explore further

Quantum tech: Semiconductor 'flipped' to insulator above room temp

113 shares

Feedback to editors