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Liquid metals shake up century-old chemical engineering processes

Liquid metals shake up century-old chemical engineering processes
Liquid gallium in a petri dish. Credit: University of Sydney/Philip Ritchie

Liquid metals could be the long-awaited solution to "greening" the chemical industry, according to researchers who tested a new technique they hope can replace energy-intensive chemical engineering processes harking back to the early 20th century.

Chemical production accounts for approximately 10–15% of total greenhouse gas emissions. More than 10% of world's total energy is also used in .

Findings published in Nature Nanotechnology offer a much-needed innovation that moves away from old, energy-intensive catalysts made from . The research is led by Professor Kourosh Kalantar-Zadeh, Head of the University of Sydney's School of Chemical and Biomolecular Engineering, and Dr. Junma Tang, who works jointly at the University of Sydney and UNSW.

A catalyst is a substance that makes chemical reactions occur faster and more easily without participating in the reaction. Solid catalysts, typically solid metals or solid compounds of metals, are commonly used in the chemical industry to make plastics, fertilizers, fuels and feedstock.

However, using solid processes is energy intensive, requiring temperatures of up to a thousand degrees centigrade.

Propylene generation using liquid gallium. Credit: Dr Junma Tang

The new process instead uses , in this case dissolving tin and nickel which gives them unique mobility, enabling them to migrate to the surface of liquid metals and react with input molecules such as canola oil. This results in the rotation, fragmentation, and reassembly of canola oil molecules into smaller organic chains, including propylene, a high-energy fuel crucial for many industries.

"Our method offers an unparalleled possibility to the chemical industry for reducing and greening chemical reactions," said Professor Kalantar-Zadeh.

"It's expected that the chemical sector will account for more than 20% of emissions by 2050," said Professor Kalantar-Zadeh. "But chemical manufacturing is much less visible than other sectors—a paradigm shift is vital."

How the process works

Atoms in liquid metals are more randomly arranged and have greater freedom of movement than solids. This allows them to easily come into contact with, and participate in, chemical reactions. "Theoretically, they can catalyze chemicals at much lower temperatures—meaning they require far less energy," Professor Kalantar-Zadeh said.

In their research, the authors dissolved high melting point nickel and tin in a gallium based liquid metal with a melting point of only 30° centigrade.

  • Liquid metals shake up century-old chemical engineering processes
    Placing liquid gallium in a Petri dish via syringe. Credit: University of Sydney/Philip Ritchie
  • Liquid metals shake up century-old chemical engineering processes
    Shaking liquid gallium in a Petri dish. Credit: University of Sydney/Philip Ritchie

"By dissolving nickel in liquid gallium, we gained access to liquid nickel at very low temperatures—acting as a 'super' catalyst. In comparison solid nickel's melting point is 1,455° centigrade. The same effect, to a lesser degree, is also experienced for tin metal in liquid gallium," Dr. Tang said.

The metals were dispersed in solvents at the atomic level. "So we have access to catalysts. Single atom is the highest surface area accessibility for catalysis which offer a remarkable advantage to the ," said Dr. Arifur Rahim, senior author and DECRA Fellow at the School of Chemical and Biomolecular Engineering.

The researchers said their formula could also be used for other by mixing metals using the low temperature processes.

"It requires such low temperature to catalyze that we could even theoretically do it in the kitchen with the gas cooktop—but don't try that at home," Dr. Tang said.

More information: Dynamic configurations of metallic atoms in the liquid state for selective propylene synthesis, Nature Nanotechnology (2023). DOI: 10.1038/s41565-023-01540-x

Journal information: Nature Nanotechnology

Citation: Liquid metals shake up century-old chemical engineering processes (2023, November 9) retrieved 5 December 2023 from
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