New silica-based adsorbent developed for selective separation of radioactive strontium from acidic medium

Prof. Huang Qunying's team from the Hefei Institutes of Physical Science of the Chinese Academy of Sciences has developed a novel inorganic silica-based adsorbent for the highly selective separation of strontium from acidic medium. The results were published in Separation and Purification Technology.

Radioactive strontium (⁹⁰Sr) is considered to be one of the most dangerous radionuclides due to its high biochemical toxicity. During the vitrification process of high-level liquid waste, the presence of ⁹⁰Sr can cause instability of the vitrification substrate, resulting in radionuclide leaching. Removal of ⁹⁰Sr can reduce the heat generation and shorten the cooling time of the vitrification substrate in the repository, which is favorable for further deep geological disposal of the radioactive waste.

To address the above issues, Prof. Huang's team developed a novel silica-based adsorbent Sb₂O₅/SiO₂ by a two-step method, i.e., vacuum impregnation followed by oxidation, and investigated the adsorption behavior of the adsorbent on strontium stable nuclide in low and high acid mediums (i.e., pH 6 and 1 M HNO₃).

The experimental results showed that the prepared adsorbent possessed good acid resistance stability and exhibited favorable adsorption on strontium stable nuclide in both low and high acid mediums. The mechanistic results revealed that the adsorption mechanism was ion exchange, and the adsorption was accompanied by charge transfer and reduction of adsorption energy.

This study not only develops a novel method for the preparation of highly stable silica-based adsorbent, but also provides relevant experimental data and theoretical basis for the selective separation of strontium in acidic environments.