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Scientists solve mystery of cubic ice

Chinese scientists solve mystery of cubic ice
Observation of cubic ice formation on graphene at 102 K by in situ cryogenic TEM. Credit: Institute of Physics

Scientists from the Institute of Physics of the Chinese Academy of Sciences (CAS) have made a major breakthrough in the study of ice by confirming the formation of pure-phase cubic ice at low-temperature interfaces.

The findings, published in Nature on March 29, have significant implications for a wide range of fields, from to climate science.

Ice is a common substance that exists in a variety of forms, depending on the conditions under which it forms. The most common form of ice, known as ice Ih, has a hexagonal lattice structure, but under certain conditions, ice can form other structures, with 20 different forms found so far.

In the case of cubic ice, known as ice Ic, a hundred years ago it was thought to be responsible for a particular type of halo around the sun or moon. In fact, the question of whether cubic ice really exists has long been controversial, as it has been difficult to perfectly detect pure-phase ice Ic in a large number of experiments.

Chinese scientists solve mystery of cubic ice
Interstitial Fe impurity (IFI) induced zero bound state (ZBS). Credit: Institute of Physics

In this study, the researchers used in-situ cryogenic transmission electron microscopy (TEM) imaging and water vapor deposition on graphene to follow the formation of ice crystallites in real time at molecular resolution.

They found that the resulting ice was pure-phase ice I, with a majority being single crystalline ice Ic and a small amount of ice Ih. The preferential nucleation of ice Ic on low-temperature substrates was demonstrated. The polymorphic diversity of ice may well explain why pure-phase ice has not previously been found by diffraction methods.

  • Chinese scientists solve mystery of cubic ice
    Two types of defects in cubic ice. Credit: Institute of Physics
  • Chinese scientists solve mystery of cubic ice
    Structural dynamics of defects in cubic ice. Credit: Institute of Physics

The cubic ice controversy has thus been resolved on the basis of direct and real-space imaging by in-situ cryogenic TEM. This achievement will contribute greatly to the development of both microscopy and ice physics.

This fundamental advance has important implications for our understanding of ice formation behavior under different conditions, which has broad applications in fields such as materials science, geology, and climate science.

More information: Lifen Wang et al, Tracking cubic ice at molecular resolution, Nature (2023). DOI: 10.1038/s41586-023-05864-5.

Journal information: Nature

Citation: Scientists solve mystery of cubic ice (2023, March 29) retrieved 7 June 2023 from
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