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Researchers develop an optimal silicon disulfide production technology to boost all-solid-state battery performance

KERI-KIT develop an optimal SiS2 production technology to boost ASSB performance
Studies on optimal SiS2 production technology published as a cover article in Journal of Materials Chemistry A. Credit: Korea Electrotechnology Research Institute

A team led by Dr. Ha Yoon-Cheol, a Principal Researcher of Next Generation Battery Research Center at the Korea Electrotechnology Research Institute (KERI) and Dr. Cheol-Min Park, a Professor of School of Materials Science and Engineering at Kumoh National Institute of Technology (KIT), has developed a low-cost production technology for silicon disulfide (SiS2) for solid-state electrolytes (argyrodite-type) that has potential to accelerate the commercialization of all-solid-state batteries (ASSBs).

ASSBs replace the liquid-state electrolytes that transfer ions between the anode and cathode with a solid less prone to fire or explosion. However, there remain many challenges to achieve commercialization, e.g., difficulties in processing and , high material cost, etc. Many research groups across the globe are working hard to tackle these challenges, and KERI has also shown several achievements.

In this study, Dr. Ha's team chose disulfide. It is widely known in academia that adding silicon disulfide to solid-state electrolytes for ASSBs helps improve ionic conductivity and moisture stability. However, the synthesis of silicon disulfide from sulfur and silicon requires a high reaction temperature, which leads to surges in the vapor pressure of sulfur, making the silicon disulfide production process particularly tricky. For this reason, silicon disulfide is a very expensive material, which currently costs about KRW 1.7 million per 20 grams.

KERI has developed a processing technology for the optimal production of silicon disulfide and paved the way for its application in solid-state electrolytes for ASSBs. The team succeeded in establishing synthesis conditions by optimizing the arrangement of sulfur and silicon powders and creating a perfectly sealed environment to withstand the vapor pressure of sulfur at 800 degrees of reaction temperature. The quality of the resulting product was comparable to the commercially available products. The team made solid-state electrolytes using their silicon disulfide and found that it had more than twice the ionic conductivity and moisture stability. Also, the optimized process will help simplify the production and reduce .

"Many researchers at home and abroad have struggled to address the elevated vapor pressure of , which required using expensive raw materials or introducing special processes," said Dr. Ha. "What we have achieved will contribute to producing silicon disulfide for cheaper and easier."

The team also applied the new silicon disulfide as an anode active material for liquid -based lithium-ion batteries and identified the destruction and recovery of layered structures during charging and discharging for the first time. The team's findings from their silicon disulfide study were published as the cover article in the recent edition of the Journal of Materials Chemistry A.

More information: Ki-Hun Nam et al, Silicon disulfide for high-performance Li-ion batteries and solid-state electrolytes, Journal of Materials Chemistry A (2023). DOI: 10.1039/D2TA08877K

Journal information: Journal of Materials Chemistry A

Provided by National Research Council of Science & Technology

Citation: Researchers develop an optimal silicon disulfide production technology to boost all-solid-state battery performance (2023, March 24) retrieved 27 May 2023 from
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