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Recyclable mobile phone batteries are a step closer with rust-busting invention

Recyclable mobile phone batteries are a step closer with rust-busting invention
Experimental setup and materials characterization. A, C Top, and, (B, D) side view schematics of the experimental setup in which a 5 µm thick oxidized Ti3C2Tz MXene film (a scanning electron microscopy (SEM) image of which is shown in (E)) is placed atop the surface reflected bulk wave (SRBW) resonator, which comprises a chipscale single-crystal LiNBO3 piezoelectric substrate, shown in (F). In (C, D), the SRBW—generated by applying a sinusoidal electrical signal from a radio frequency (RF) source to interdigital transducer (IDT) electrodes photolithographically patterned onto the LiNbO3 substrate—propagates along and through the substrate and is transmitted into the Ti3C2Tz MXene film through a thin water coupling layer. In the control experiment (A, B), the SRBW is not excited. G Powder x-ray diffraction (XRD), and, (H) Raman spectra of the pristine, control (oxidized) and SRBW-irradiated films MXenes at different powers. Credit: Nature Communications (2023). DOI: 10.1038/s41467-022-34699-3

Mobile phone batteries with a lifetime up to three times longer than today's technology could be a reality thanks to an innovation led by engineers at RMIT University.

Rather than disposing of batteries after two or three years, we could have recyclable batteries that last for up to nine years, the team says, by using high-frequency to remove rust that inhibits battery performance.

The research is published in Nature Communications.

Only 10% of used handheld batteries, including for mobile phones, are collected for recycling in Australia, which is low by international standards. The remaining 90% of batteries go to landfill or are disposed of incorrectly, which causes considerable damage to the environment.

The high cost of recycling lithium and other materials from batteries is a major barrier to these items being reused, but the team's innovation could help to address this challenge.

The team are working with a nanomaterial called MXene, a class of materials that they say promises to be an exciting alternative to lithium for batteries in the future.

Leslie Yeo, Distinguished Professor of Chemical Engineering from RMIT's School of Engineering and lead senior researcher, said MXene was similar to graphene with .

"Unlike graphene, MXenes are highly tailorable and open up a whole range of possible technological applications in the future," said Yeo.

The big challenge with using MXene was that it rusted easily, thereby inhibiting electrical conductivity and rendering it unusable, he said, adding, "To overcome this challenge, we discovered that sound waves at a certain frequency remove rust from MXene, restoring it to close to its original state."

The team's innovation could one day help to revitalize MXene batteries every few years, extending their lifetime up to three times, he said.

"The ability to prolong the shelf life of MXene is critical to ensuring its potential to be used for commercially viable electronic parts," Yeo said.

Recyclable mobile phone batteries a step closer with rust-busting invention
Hossein Alijani, a Ph.D. researcher, with the new rust-busting device. Credit: RMIT University

How the innovation works

Co-lead author Hossein Alijani, a Ph.D. candidate from RMIT's School of Engineering, said the greatest challenge with using MXene was the rust that forms on its surface in a humid environment or when suspended in watery solutions.

"Surface oxide, which is rust, is difficult to remove, especially on this material, which is much, much thinner than a human hair," said Alijani. "Current methods used to reduce rely on the chemical coating of the material, which limits the use of the MXene in its native form. In this work, we show that exposing an oxidized MXene film to vibrations for just a minute removes the rust on the film. This simple procedure allows its electrical and electrochemical performance to be recovered."

The potential applications of the team's work

The team says their work to remove rust from Mxene opens the door for the nanomaterial to be used in a wide range of applications in energy storage, sensors, wireless transmission and environmental remediation.

Associate Professor Amgad Rezk from RMIT's School of Engineering, one of the lead senior researchers, said the ability to quickly restore oxidized materials to an almost pristine state represented a gamechanger in terms of the circular economy.

"Materials used in electronics, including batteries, generally suffer deterioration after two or three years of use due to rust forming," said Rezk. "With our method, we can potentially extend the lifetime of battery components by up to three times."

While the innovation is promising, the team needs to work with industry to integrate its acoustics device into existing manufacturing systems and processes. The team is also exploring the use of their invention to remove oxide layers from other materials for applications in sensing and renewable energy.

"We are keen to collaborate with industry partners so that our method of removal can be scaled up," Yeo said.

More information: Heba Ahmed et al, Recovery of oxidized two-dimensional MXenes through high frequency nanoscale electromechanical vibration, Nature Communications (2023). DOI: 10.1038/s41467-022-34699-3

Journal information: Nature Communications

Provided by RMIT University

Citation: Recyclable mobile phone batteries are a step closer with rust-busting invention (2023, January 24) retrieved 16 April 2024 from
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