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Researchers discover new process to create freestanding membranes of 'smart' materials

Researchers discover new process to create freestanding membranes of 'smart' materials
University of Minnesota Twin Cities Professor Bharat Jalan is co-leading a team that has developed a new method for making nano-membranes of “smart” materials, which will allow scientists to harness their unique properties for use in devices such as sensors and flexible electronics. Credit: Olivia Hultgren

A University of Minnesota Twin Cities-led team of scientists and engineers has developed a new method for making thin films of perovskite oxide semiconductors, a class of "smart" materials with unique properties that can change in response to stimuli like light, magnetic fields, or electric fields.

The discovery will allow researchers to harness these properties and even combine them with other emerging nano-scale to make better devices such as sensors, , and flexible electronics.

The paper is published in Science Advances.

Producing materials in thin-film form makes them easier to integrate into smaller components for . Many are made using a technique called epitaxy, which consists of placing atoms of a material on a substrate, or a template of sorts, to create a thin sheet of material, one atomic layer at a time. However, most thin films created via epitaxy are "stuck" on their host substrate, limiting their uses. If the thin film is detached from the substrate to become a freestanding membrane, it becomes much more functional.

The University of Minnesota-led team has found a new way to successfully create a membrane of a particular metal oxide——and their method circumvents several issues that have plagued the synthesis of freestanding metal oxide films in the past.

"We have created a process where we can make a freestanding membrane of virtually any oxide material, exfoliate it, and then transfer it onto any subject of interest we want," said Bharat Jalan, a senior author on the paper and a professor and Shell Chair in the University of Minnesota Department of Chemical Engineering and Materials Science. "Now, we can benefit from the functionality of these materials by combining them with other nano-scale materials, which would enable a wide range of highly functional, highly efficient devices."

Making freestanding membranes of "smart" oxide materials is challenging because the atoms are bonded in all three dimensions, unlike in a two-dimensional material, such as graphene. One method of making membranes in oxide materials is using a technique called remote epitaxy, which uses a layer of graphene as an intermediary between the substrate and the thin-film material.

This approach allows the thin-film oxide material to form a thin film and be peeled off, like a piece of tape, from the substrate, creating a freestanding . However, the biggest barrier to using this method with metal oxides is that the oxygen in the material oxidizes the graphene on contact, ruining the sample.

Using hybrid , a technique pioneered by Jalan's lab at the University of Minnesota, the researchers were able to get around this issue by using titanium that was already bonded to oxygen. Plus, their method allows for automatic stoichiometric control, meaning they can automatically control the composition.

"We showed for the first time, and conclusively by doing several experiments, that we have a new method which allows us to make complex oxide while ensuring that graphene is not oxidized. That's a major milestone in synthesis science," Jalan said. "And, we now have a way to make these complex membranes with an automatic stoichiometric control. No one has been able to do that."

The materials scientists on Jalan's team worked closely with engineering researchers in University of Minnesota Department of Electrical and Computer Engineering Professor Steven Koester's lab, which focuses on making 2D materials.

"These complex oxides are a broad class of materials that have a lot of really important innate functions to them," said Koester, also a senior author of the study and the director of the Minnesota Nano Center at the University of Minnesota Twin Cities. "Now, we can think about using them to make extremely small transistors for electronic devices, and in a wide array of other applications including flexible sensors, smart textiles, and non-volatile memories."

More information: Hyojin Yoon et al, Freestanding epitaxial SrTiO3 nanomembranes via remote epitaxy using hybrid molecular beam epitaxy, Science Advances (2022). DOI: 10.1126/sciadv.add5328

Journal information: Science Advances

Citation: Researchers discover new process to create freestanding membranes of 'smart' materials (2023, January 3) retrieved 17 April 2024 from
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