Scientists synthesize an unusual superconducting barium superhydride

Scientists synthesize an unusual superconducting barium superhydride
Credit: Pavel Odinev / Skoltech

A group of scientists from Russia, China and the United States predicted and then experimentally obtained barium superhydrides, new unusual superconductors. The study was published in Nature Communications.

Chemists and physicists have been hunting down room-temperature since the first half of the 20th century. Initially, high hopes were placed on but, as it later transpired, solid metallic can become superconducting only at extremely high pressures of several million atmospheres. Chemists then tried adding other elements to hydrogen in the hope of attaining superconductivity by stabilizing the metallic state under less challenging conditions. Scientists, including the research team led by Skoltech Professor Artem R. Oganov, predicted and experimentally obtained a set of compounds with an unusually large number of hydrogen atoms, such as ThH9, ThH10, PrH9, NdH7, NdH9, YH6, and so on. Yet, the race for higher hydrogen content in such bizarre hydrides and especially for higher superconducting transition temperature is still on.

In their latest study, scientists from Oganov's laboratory and their colleagues from China and the United States analyzed all possible barium hydrides using the unique theoretical approaches developed by Oganov and his students and implemented in their USPEX code (, and finally selected BaH12, a compound with one of the highest hydrogen contents. The researchers obtained the compound experimentally, demonstrated its superconductivity and studied its . BaH12 turned out to be quite a remarkable compound with a structure formed by molecular groups of two and three hydrogen atoms and acting as a molecular superconductor. Thanks to its molecular structure, BaH12 is not a high-temperature superconductor: its is -253 °C. The study marks significant progress in understanding what kind of structures may someday perform as room-temperature superconductors in real devices.

"On October 14, 2020, American scientists reported the discovery of a room-temperature superconductor, ushering in an era of room superconductivity. The composition of the new superconductor has not been disclosed but its room-temperature superconductivity has been convincingly demonstrated. A century-long dream has come true! Recall that superconductivity was first observed in mercury at -269 C over 100 years ago. The new material is unlikely to have immediate practical applications, as it can only be synthesized in microscopic amounts under extremely high pressures of nearly three million atmospheres. We should continue searching for new materials and studying their properties so that we could someday figure out how to achieve room-temperature superconductivity under normal pressure," Oganov says.

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More information: Wuhao Chen et al. Synthesis of molecular metallic bariumsuperhydride: pseudocubic BaH12. Nature Communications
Journal information: Nature Communications

Citation: Scientists synthesize an unusual superconducting barium superhydride (2021, January 11) retrieved 17 May 2022 from
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