Functionalized surfaces: Cylindrical micellar brushes with controlled length tailored chemical options

A way to functionalize surfaces with cylindrical micelle brushes with controlled length tailored chemical options
Seeded growth of hydrophobic PFS53-b-PDMS418 micellar brushes on a silicon wafer. (A) Schematic illustration of the process, which involves the immobilization of PFS36-b-P2VP502 seeds (Ln = 139 nm, Lw/Ln = 1.04) on a silicon wafer via H-bonding (and probably also assisted by electrostatic interactions) followed by crystallization-driven epitaxial growth of PFS53-b-PDMS418 micellar brushes. (B to D) AFM height images of PFS53-b-PDMS418 micellar brushes of different densities formed under a constant unimer-to-seed mass ratio (1:1 in the feed) but different seed concentrations: (B) 0.125 mg/ml, (C) 0.25 mg/ml, (D) 0.5 mg/ml. (E) Plot of the dependence of contact angle (CA) value on seed concentration. Insets are photographs of the water droplets on the micellar brush–coated silicon wafers prepared with seed concentrations of 0.025 mg/ml (left) and 0.5 mg/ml (right). (F to H) AFM height images of PFS53-b-PDMS418 micellar brushes formed at a constant seed concentration (0.5 mg/ml) but different amounts of unimers: (F) 2 μl, (G) 4 μl, (H) 6 μl. Insets in (B) and (H) are enlargements of the boxed areas. (I) Plot of the dependence of CA value on unimer amount. Error bars in (E) and (I) denote SD of the measured CA values (≥5 locations for each sample). Credit: Science (2019). DOI: 10.1126/science.aax9075

A team of researchers affiliated with multiple institutions in China has developed a way to functionalize surfaces with cylindrical micelle brushes with controlled length and tailored chemical options. In their paper published in the journal Science, the group outlines their method, give specific examples, and discuss possible uses for it. Alejandro Presa Soto with the University of Oviedo has published a Perspective piece in the same journal issue discussing the importance of patterned surface design and its many uses, along with a discussion of the work done by the team in China.

As Presa Soto notes, the design of patterned surfaces in a rational manner represents new avenues for fine-tuning composition and functionality in base materials. He further notes that doing so in ways that can be expanded for use with other materials is optimal. In this new effort, the team in China has done just that. They have developed a bottom-up strategy for fabrication of nanostructures on a host of different surfaces.

The method by the team involved starting with PFS crystallite and poly(2-vinylpyridine) micelle seeds placed on the substrate. Doing so resulted in PFS copolymers growing epitaxially from the seeds. Next, cylindrical micellar brushes formed due to crystallization self-assembly. That was followed by unimers switching to PFS-P2VP—resulting in the formation of comicelles. In their example (using and ), attachment occurred due to hydrogen bonding between pyridine groups of P2VP coronas and the hydroxyl groups. The researchers note that the ends of the crystallite seeds had PFS cores which remained active, allowing for the addition of more PFS-based BCPs. They further note that the micellar brushes could be functionalized specifically at the coronas by using gold nanoparticles that are able to catalyze certain chemical reactions. They suggest the technique could be used for allowing control over multiple properties of a such as length, density and chemistry—using micellar brushes. They further suggest the brushes could be outfitted with other molecules or nanoparticles to facilitate different sorts of catalysis, chemical separation or even antibacterial applications. Presa Soto notes that the approach is a step forward in the search for general and simple ways to create functional surfaces that have specific chemical properties.

More information: Jiandong Cai et al. Tailored multifunctional micellar brushes via crystallization-driven growth from a surface, Science (2019). DOI: 10.1126/science.aax9075

Journal information: Science

© 2019 Science X Network

Citation: Functionalized surfaces: Cylindrical micellar brushes with controlled length tailored chemical options (2019, November 29) retrieved 22 July 2024 from
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