When rotated at a 'magic angle,' graphene sheets can form an insulator or a superconductor

March 5, 2018 by Jennifer Chu, Massachusetts Institute of Technology
Physicists at MIT and Harvard University have found that graphene, a lacy, honeycomb-like sheet of carbon atoms, can behave at two electrical extremes: as an insulator, in which electrons are completely blocked from flowing; and as a superconductor, in which electrical current can stream through without resistance. Credit: MIT

It's hard to believe that a single material can be described by as many superlatives as graphene can. Since its discovery in 2004, scientists have found that the lacy, honeycomb-like sheet of carbon atoms - essentially the most microscopic shaving of pencil lead you can imagine - is not just the thinnest material known in the world, but also incredibly light and flexible, hundreds of times stronger than steel, and more electrically conductive than copper.

Now physicists at MIT and Harvard University have found the wonder material can exhibit even more curious electronic properties. In two papers published today in Nature, the team reports it can tune graphene to behave at two electrical extremes: as an insulator, in which electrons are completely blocked from flowing; and as a superconductor, in which electrical current can stream through without resistance.

Researchers in the past, including this team, have been able to synthesize graphene superconductors by placing the material in contact with other superconducting metals - an arrangement that allows graphene to inherit some superconducting behaviors. This time around, the team found a way to make graphene superconduct on its own, demonstrating that superconductivity can be an intrinsic quality in the purely carbon-based material.

The physicists accomplished this by creating a "superlattice" of two stacked together - not precisely on top of each other, but rotated ever so slightly, at a "magic angle" of 1.1 degrees. As a result, the overlaying, hexagonal honeycomb pattern is offset slightly, creating a precise moiré configuration that is predicted to induce strange, "strongly correlated interactions" between the electrons in the graphene sheets. In any other stacked configuration, graphene prefers to remain distinct, interacting very little, electronically or otherwise, with its neighboring layers.

The team, led by Pablo Jarillo-Herrero, an associate professor of physics at MIT, found that when rotated at the magic angle, the two sheets of graphene exhibit nonconducting behavior, similar to an exotic class of known as Mott insulators. When the researchers then applied voltage, adding small amounts of electrons to the graphene superlattice, they found that, at a certain level, the electrons broke out of the initial insulating state and flowed without resistance, as if through a superconductor.

"We can now use graphene as a new platform for investigating unconventional superconductivity," Jarillo-Herrero says. "One can also imagine making a superconducting transistor out of graphene, which you can switch on and off, from superconducting to insulating. That opens many possibilities for quantum devices."

A 30-year gap

A material's ability to conduct electricity is normally represented in terms of energy bands. A single band represents a range of energies that a material's electrons can have. There is an energy gap between bands, and when one band is filled, an electron must embody extra energy to overcome this gap, in order to occupy the next empty band.

A material is considered an insulator if the last occupied energy band is completely filled with electrons. Electrical conductors such as metals, on the other hand, exhibit partially filled energy bands, with empty energy states which the electrons can fill to freely move.

Mott insulators, however, are a class of materials that appear from their band structure to conduct electricity, but when measured, they behave as insulators. Specifically, their energy bands are half-filled, but because of strong electrostatic interactions between electrons (such as charges of equal sign repelling each other), the material does not conduct electricity. The half-filled band essentially splits into two miniature, almost-flat bands, with electrons completely occupying one band and leaving the other empty, and hence behaving as an insulator.

"This means all the electrons are blocked, so it's an insulator because of this strong repulsion between the electrons, so nothing can flow," Jarillo-Herrero explains. "Why are Mott insulators important? It turns out the parent compound of most high-temperature superconductors is a Mott insulator."

In other words, scientists have found ways to manipulate the electronic properties of Mott insulators to turn them into superconductors, at relatively high temperatures of about 100 Kelvin. To do this, they chemically "dope" the material with oxygen, the atoms of which attract electrons out of the Mott insulator, leaving more room for remaining electrons to flow. When enough oxygen is added, the insulator morphs into a superconductor. How exactly this transition occurs, Jarillo-Herrero says, has been a 30-year mystery.

"This is a problem that is 30 years and counting, unsolved," Jarillo-Herrero says. "These high-temperature superconductors have been studied to death, and they have many interesting behaviors. But we don't know how to explain them."

A precise rotation

Jarillo-Herrero and his colleagues looked for a simpler platform to study such unconventional physics. In studying the in graphene, the team began to play around with simple stacks of graphene sheets. The researchers created two-sheet superlattices by first exfoliating a single flake of graphene from graphite, then carefully picking up half the flake with a glass slide coated with a sticky polymer and an insulating material of boron nitride.

They then rotated the glass slide very slightly and picked up the second half of the graphene flake, adhering it to the first half. In this way, they created a superlattice with an offset pattern that is distinct from graphene's original honeycomb lattice.

The team repeated this experiment, creating several "devices," or graphene superlattices, with various angles of rotation, between 0 and 3 degrees. They attached electrodes to each device and measured an electrical current passing through, then plotted the device's resistance, given the amount of the original current that passed through.

"If you are off in your rotation angle by 0.2 degrees, all the physics is gone," Jarillo-Herrero says. "No superconductivity or Mott insulator appears. So you have to be very precise with the alignment angle."

At 1.1 degrees - a rotation that has been predicted to be a "magic angle" - the researchers found the graphene superlattice electronically resembled a flat band structure, similar to a Mott insulator, in which all electrons carry the same energy regardless of their momentum.

"Imagine the momentum for a car is mass times velocity," Jarillo-Herrero says. "If you're driving at 30 miles per hour, you have a certain amount of kinetic energy. If you drive at 60 miles per hour, you have much higher energy, and if you crash, you could deform a much bigger object. This thing is saying, no matter if you go 30 or 60 or 100 miles per hour, they would all have the same energy."

"Current for free"

For electrons, this means that, even if they are occupying a half-filled energy band, one electron does not have any more energy than any other electron, to enable it to move around in that band. Therefore, even though such a half-filled should act like a conductor, it instead behaves as an insulator - and more precisely, a Mott insulator.

This gave the team an idea: What if they could add electrons to these Mott-like superlattices, similar to how scientists doped Mott insulators with oxygen to turn them into superconductors? Would graphene assume superconducting qualities in turn?

To find out, they applied a small gate voltage to the "magic-angle graphene superlattice," adding small amounts of electrons to the structure. As a result, individual electrons bound together with other electrons in graphene, allowing them to flow where before they could not. Throughout, the researchers continued to measure the electrical resistance of the material, and found that when they added a certain, small amount of , the electrical current flowed without dissipating energy - just like a superconductor.

"You can flow current for free, no wasted, and this is showing graphene can be a superconductor," Jarillo-Herrero says.

Perhaps more importantly, he says the researchers are able to tune to behave as an or a superconductor, and any phase in between, exhibiting all these diverse properties in one single device. This is in contrast to other methods, in which scientists have had to grow and manipulate hundreds of individual crystals, each of which can be made to behave in just one electronic phase.

"Usually, you have to grow different classes of materials to explore each phase," Jarillo-Herrero says. "We're doing this in-situ, in one shot, in a purely carbon device. We can explore all those physics in one device electrically, rather than having to make hundreds of devices. It couldn't get any simpler."

Explore further: Atomically thin building blocks could make optoelectrical devices more efficient

More information: Correlated Insulator Behaviour at Half-Filling in Magic Angle Graphene Superlattices, Nature (2018). nature.com/articles/doi:10.1038/nature26154

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not rated yet Mar 09, 2018
These observations should introduce a new impulse into research of superconductivity within graphite, which is still ignored by mainstream physics, despite that evidence for it is steadily growing. The reasons why these findings are ignored is, the mainstream superconductivity research establishment still adheres on classical BCS theory based on Cooper pairs, which these findings indeed violate too. The actual mechanism of superconductivity is in compression of conductive electrons, which occurs between areas of twisted graphene too. These electrons indeed repel mutually which would lead into buckling of layers in areas where the electrons get squeezed the most. This buckling can be eliminated by gluing the graphene layers by inert molecules, which is just the trick on which observations of superconductive graphene were based.
not rated yet Mar 09, 2018
What if they could add electrons to these Mott-like superlattices, similar to how scientists doped Mott insulators with oxygen to turn them into superconductors? Would graphene assume superconducting qualities in turn?
The doping of graphene by small amount of electron sucking or repelling atoms would have the same effect too. Ideally these dopant atoms should be applied just to areas, which are subject of highest compression of electron fluid, because when applied to another places, they would have opposite effect.
For me the graphite may not be so practically interesting as a superconductor, but rather like cheap material utilizing overunity effects, which squeezed Dirac electrons tend to exhibit by their violation of thermodynamic time arrow. For utilization these effects the electrons within superconductive islands even must not remain connected mutually, we could therefore utilize pseudogap phase, which may be even less conductive than the graphite in its bulk state.

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