Slow 'hot electrons' could improve solar cell efficiency

January 16, 2018, University of Groningen
Professor of Photophysics and Optoelectronics Maria Antonietta Loi, Zernike Institute for Advanced Materials, University of Groningen. Credit: Sylvia Germes

Photons with energy higher than the band gap of the semiconductor absorbing them give rise to what are known as hot electrons. The extra energy in respect to the band gap is lost very fast, as it is converted into heat and does not contribute to the voltage. University of Groningen Photophysics and Optoelectronics Professor Maria Antonietta Loi has now found a material in which these hot electrons retain their high energy levels for much longer. This might make it possible to use more of their energy to obtain a higher voltage. Her results were published on 16 January in Nature Communications.

The efficiency of is hampered by a Goldilocks problem: Photons need to have just the right amount of energy to be converted into , which contribute to the voltage. Too little energy, and the photons pass right through the solar panel. Too much, and the excess energy disappears as heat. This is due to the creation of hot (high-energy) electrons. Before they can be extracted from the solar cells, these first give off their excess energy by causing vibrations in the crystalline material of the solar panel. "This energy loss puts a limit to the maximum efficiency of solar cells," explains Loi.

She is working on a special type of solar cell that is made of organic-inorganic hybrid perovskites. Perovskites are named after a mineral that has the chemical formula ABX3. In the X position, anions form an octahedron, while in the A position, cations form a cube around them, while a central cation takes the B position. Many materials in the perovskite family adopt this crystal structure. Hybrid perovskites contain organic cations in the A position.

Most hybrid-perovskite solar cells contain lead, which is toxic. Loi's group recently published a paper describing a record-breaking 9 percent efficiency in a hybrid-perovskite solar cell containing harmless tin instead of lead. "When we studied this material further, we observed something strange," she continues. The results could only mean that the hot electrons produced in the tin-based solar cells took about a thousand times longer than usual to dissipate their .

"The hot electrons gave off their energy after several nanoseconds instead of some hundred femtoseconds. Finding such long-lived hot electrons is what everybody in this field is hoping for," says Loi. Their longer lifespan makes it possible to harvest these electrons' energy before it turns into heat. "This means we could harvest electrons with a higher energy and thus create a higher voltage in the solar cell." Theoretical calculations show that by harvesting the hot electrons, the for hybrid-perovskite could increase from 33 to 66 percent.

The next step is to find out why the tin-based hybrid perovskite slows down the decay of hot electrons. Then new perovskite materials could be designed with even slower hot electrons. "These tin-based perovskites could be a game changer, and could ultimately make a big contribution to providing clean and sustainable in the future."

Explore further: Twisting molecule wrings more power from solar cells

More information: Hong-Hua Fang et al, Long-lived hot-carrier light emission and large blue shift in formamidinium tin triiodide perovskites, Nature Communications (2018). DOI: 10.1038/s41467-017-02684-w

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mackita
not rated yet Jan 16, 2018
large blue shift in formamidinium tin triiodide perovskites
Unfortunately the formamidium-based perovskites are even less stable on air and prone to sunbleaching, than these classical ones based on alkylamines.. Their potential for utilization of hot electrons therefore comes at price: it's true that the hot electrons get thermalized more slowly - but from the same reason these evil electrons also have more time for destruction of organic part of molecule...
Merrit
not rated yet Jan 16, 2018
There is a lot of research being done for different types of materials, but the answer is likely to come in the form of metameterials. Something like breaking the light and focusing it in such a way for it to be converted to electricity more efficiently. Also, finding a way to efficiently convert the heat back to electricity

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