The universal truth about sticky surfaces

The universal truth about sticky surfaces
A better understanding of purification setups will help material scientists to develop better filtering systems. Credit: Panther Media GmbH / Alamy

Trapping molecules on custom-designed porous surfaces becomes easier with a new model that unifies previous theories of adsorption.

Many purification tools, from simple charcoal filters to complex desalination plants, rely on solids with millions of tiny pores to capture and remove contaminants without chemically binding to them. Now, a KAUST team has identified the key factors that connect adsorption on different kinds of porous surfaces, solving century-old problems of predicting uptake on unknown substances.

In the early 1900s, the concept of adsorption isotherms emerged to describe how adsorbents behave in the presence of steadily increasing amounts of molecules. These graphs have distinct shapes that depend on atom-scale properties-for example, whether particles stick in single layers or multilayers-and quickly became essential for designing and understanding purification setups. The majority of absorbents, chemists found, could be sorted into one of six isotherms after a few experimental measurements.

However, modern absorbents with heterogeneous pore structures, such as (MOFs), are proving more difficult to model. While these materials benefit from high-throughput testing of numerous samples, the need for individual isotherm measurements slows discovery considerably-a situation experienced by Professor Kim Choon Ng at KAUST's Water Desalination and Reuse Center.

The universal truth about sticky surfaces
SEM images of the porous surface at increasing microscopy strength (from top left). Credit: KAUST

"We were working to improve treatment of seawater, and using isotherms was very tedious," says Ng. "Everyone had to do their own trial and error work for particular applications, and there was no real theory to help people design absorbents."

With researchers Muhammad Burhan and Muhammad Shahzad, Ng aimed to find out how the different isotherms could be combined into a single universal model. They proposed subdividing surfaces with nanometer-scale pore variations into tiny patches that adsorb guest molecules under similar thermodynamic and kinetic conditions. By introducing a probability factor to define the of each patch, the team created a mathematical function capable of spotting significant characteristics of adsorbent surfaces.

The universal truth about sticky surfaces
Differences in pore sizes on absorbent surfaces can be better understood with a model that spots tiny regions where gases attach at similar energies Reproduced with permission under creative commons licence from reference. Credit: KAUST

Comparisons between predictions generated by the universal model and literature isotherms revealed the power of the new approach. Not only did the theoretical data match the measured experiments for all six isotherm categories, but multiple peaks appeared in the energy distribution plots when heterogeneous conditions are detected-parameters that may prove critical for development of innovative materials with fine-tuned sorption capabilities.

"Each adsorbent-adsorbate pair has its own distinct energy distribution function, which allows us to capture all the information in the isotherms," explains Ng. "Materials scientists should be able to use techniques such as acidification to expand pore sizes in metal-organic frameworks and shift their energy distribution to increase uptake."

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More information: Kim Choon Ng et al. A Universal Isotherm Model to Capture Adsorption Uptake and Energy Distribution of Porous Heterogeneous Surface, Scientific Reports (2017). DOI: 10.1038/s41598-017-11156-6
Journal information: Scientific Reports

Citation: The universal truth about sticky surfaces (2017, December 20) retrieved 8 July 2020 from
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