Two-dimensional MXene materials get their close-up

March 14, 2017 by Dawn Levy
Xiahan Sang (left) and Raymond Unocic of Oak Ridge National Laboratory used scanning transmission electron microscopy and electron energy loss spectroscopy to reveal atomic positions and local electronic properties of 2D MXene that had been etched and exfoliated from a 3D crystal. Credit: Oak Ridge National Laboratory, U.S. Dept. of Energy; photographer Carlos Jones

Researchers have long sought electrically conductive materials for economical energy-storage devices. Two-dimensional (2-D) ceramics called MXenes are contenders. Unlike most 2-D ceramics, MXenes have inherently good conductivity because they are molecular sheets made from the carbides and nitrides of transition metals like titanium.

MXenes were co-discovered by Michael Naguib, now a Wigner Fellow at the Department of Energy's Oak Ridge National Laboratory, while pursuing his PhD at Drexel University in 2011. MXene layers can be combined to engineer ultrathin electronics, sensors, batteries, supercapacitors and catalysts. About 20 MXenes have since been reported.

Recently, ORNL scientists using state-of-the-art scanning , or STEM, provided the first direct evidence of the atomic-defect configurations in a titanium-carbide MXene synthesized at Drexel University. Published in ACS Nano, a journal of the American Chemical Society, the study coupled atomic-scale characterization and electrical property measurements with theory-based simulation.

‪"Using atomic-resolution scanning transmission electron microscopy imaging, we visualized defects and defects clusters in MXene that are very important for future nano electronic devices and catalytic applications," said lead author Xiahan Sang of the Center for Nanophase Materials Sciences (CNMS), a DOE Office of Science User Facility at ORNL.

"Atomic-level defects can be engineered into materials to enable new functionalities," said senior author Raymond Unocic of CNMS. "Understanding these defects is critical for advancing materials."

Atomic imaging from different perspectives was the key to revealing MXene's structure. When the sample is aligned with the electron beam within a STEM instrument, the viewer cannot tell how many sheets lie under the top layer. But simply tilt the sample, and differences readily appear. For example, a multi-sheet layer is made of stacked atoms, a structure that forms a blurred image when the layer is tilted. The appearance of sharp atomic images under different tilting conditions unambiguously proved the single-layer structure of the MXene.

Easy mass-production of a good 2-D conductor

MXenes are made from a three-dimensional (3-D) bulk crystal called MAX (the "M" denotes a transition metal; "A," an element, such as aluminum or silicon, from a specific chemical group; and "X," either carbon or nitrogen). In the MAX lattice from which the MXene explored in this study emerged, three layers of titanium carbide are sandwiched between aluminum layers.

The Drexel researchers improved a technique developed in 2011 and altered in 2014 to synthesize MXene from the bulk MAX phase using acids. The improved method is called minimally intensive layer delamination, or MILD. "By going with MILD, we ended up with large flakes of high-quality MXene," said Mohamed Alhabeb, a PhD student in materials science at Drexel University, who accomplished this feat with another PhD student, Katherine Van Aken, under the leadership of one of the co-discoverers of MXenes, Distinguished University Professor and Director of the A.J. Drexel Nanomaterials Institute Yury Gogotsi.

To synthesize free-standing MXene flakes, the Drexel team first treated bulk MAX with an etchant of fluoride salt and hydrochloric acid to selectively remove unwanted layers of aluminum from between titanium carbide layers. Then they manually shook the etched material to separate and collect the titanium carbide layers. Each layer is five atoms thick and is made of carbon atoms binding three titanium sheets. Etching and exfoliating MAX produces many of these free-standing MXene layers. This relatively simple technique may enable manufacturing-scale production.

Etching creates defects—vacant spaces that emerge as titanium atoms are pulled from surfaces. "Defects" are actually good in many applications of materials. They can be introduced into a material and manipulated to enhance its useful catalytic, optical or electronic properties.

The greater the concentration of etchant, the larger the number of defects created, the study found. "We have the capability to tune the defect concentration, which could be used to tailor physicochemical properties for energy storage and conversion devices," Sang said.

Moreover, the number of defects did not strongly affect MXene's electrical conductivity. At CNMS, Ming-Wei Lin and Kai Xiao measured physical properties, including electrical conductivity, of various promising 2-D materials. They found MXene was an order of magnitude less conductive than a perfect graphene sheet but two orders of magnitude more conductive than metallic molybdenum disulfide.

Using modeling and simulation, ORNL's Paul Kent and Yu Xie calculated the energy needed to create atomic configurations of defects that Sang's STEM showed were prevalent.

Next the researchers plan to tune down to the atomic level to tailor specific behaviors.

Explore further: Team finds new energy storage capabilities between layers of 2-D materials

More information: Xiahan Sang et al. Atomic Defects in Monolayer Titanium Carbide (Ti3C2Tx) MXene, ACS Nano (2016). DOI: 10.1021/acsnano.6b05240

Related Stories

Bending—but not breaking—in search of new materials

November 11, 2014

Making a paper airplane in school used to mean trouble. Today it signals a promising discovery in materials science research that could help next-generation technology -like wearable energy storage devices- get off the ground. ...

Shaping the future of energy storage with conductive clay

November 26, 2014

In the race to find materials of ever increasing thinness, surface area and conductivity to make better performing battery electrodes, a lump of clay might have just taken the lead. Materials scientists from Drexel University's ...

Recommended for you

Chemists create 3-D printed graphene foam

June 21, 2017

Nanotechnologists from Rice University and China's Tianjin University have used 3-D laser printing to fabricate centimeter-sized objects of atomically thin graphene.

Plant inspiration could lead to flexible electronics

June 21, 2017

Versatile, light-weight materials that are both strong and resilient are crucial for the development of flexible electronics, such as bendable tablets and wearable sensors. Aerogels are good candidates for such applications, ...

Neuron transistor behaves like a brain neuron

June 20, 2017

(Phys.org)—Researchers have built a new type of "neuron transistor"—a transistor that behaves like a neuron in a living brain. These devices could form the building blocks of neuromorphic hardware that may offer unprecedented ...

0 comments

Please sign in to add a comment. Registration is free, and takes less than a minute. Read more

Click here to reset your password.
Sign in to get notified via email when new comments are made.