Rusty steel triggers oxygen evolution

Rusty steel triggers oxygen evolution

Electrocatalytic water splitting is one of the most promising next generation technologies for environmentally friendly and inexpensive energy conversion and storage. However, one of its biggest obstacles is the sluggishness of the oxidation reaction, which is key to the whole process. State-of-the-art technology relies on metal oxide electrocatalysts, but both cost and performance still need to be improved. In the journal Angewandte Chemie, Chinese scientists have now introduced oxidized, that is, rusty, stainless-steel plates as excellent electrocatalysts for oxygen evolution. That technology could represent a surprisingly simple approach toward solving a long-standing problem.

The reaction represents the conversion of water into oxygen and hydrogen. Although this principle used in plants is the most important energy converting reaction on Earth, it is difficult to implement as industrial processes. One of the key challenges is the development of suitable catalysts to accelerate the sluggish of water for the generation of oxygen. The requirements for possible electrocatalysts are manifold, including durability and low cost. The best electrocatalysts considered today are the oxides of the heavy metals ruthenium and iridium, but they are expensive and scarce, whereas the cheaper ones based on earth-abundant transition metals need other improvements. In an unusual approach, Xinbo Zhang at the Chinese Academy of Sciences and his colleagues have turned a simple stainless steel plate electrode into a highly efficient electrocatalyst just by artificially corroding its surface.

This planned corrosion includes hydrothermal and electrochemical treatment in alkali solution, and it renders the former smooth and plain surface brownish-rusty. Rusty, but perfect for catalysis, as especially nickel hydroxides, released from the steel, are known to be excellent electrocatalysts. And second, as the scientists point out, the rougher and more basic surface is perfectly wettable, it provides excellent contact to the current collector, is stable, and robust.

Neither long-term stability seems to be a problem nor the necessary reactivation of the active surface, which can be carried out by the same process used for introducing the artificial corrosion. Alluding to the low reputation of "rust" as seemingly deteriorated material, the scientists say their method is "turning waste into treasure". Their approach was shown to be practical, efficient, and could be a very promising start for next generation water splitting technologies.

More information: Haixia Zhong et al, In Situ Activating Ubiquitous Rust towards Low-Cost, Efficient, Free-Standing, and Recoverable Oxygen Evolution Electrodes, Angewandte Chemie International Edition (2016). DOI: 10.1002/anie.201604040

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