Gases drawn into particles stay there

Apr 09, 2012
SPLAT II provides measurements of particles with unprecedented sensitivity and precision to scientists such as Alla Zelenyuk.

(Phys.org) -- Contrary to expectations, formation and growth of complex organic particles generated during oxidation of volatile organic molecules by ozone and nitrate follows a non-equilibrium path, according to a recent study in the Proceedings of the National Academy of Sciences.

The formation kinetic data show that the organic nitrates do not dissolve in the , but rather condense on quasi-solid particles' surfaces, where they are trapped, proving unequivocally that these particles are not in a liquid state. The study was conducted by University of California, Irvine chemist Prof. Barbara Finlayson-Pitts in collaboration with Dr. Alla Zelenyuk at Pacific Northwest National Laboratory.

These findings represent an important step in the development of a fundamental mechanistic understanding of the formation and properties of complex organic particles, putting into question prevailing assumptions used in current aerosol models. Reformulation of aerosol models would affect the predicted formation and evolution of , their role in heterogeneous chemistry, their projected impacts on air quality, visibility, and climate, and hence the development of reliable control strategies.

SPLAT, a one-of-a-kind single spectrometer that resides in EMSL, was used to characterize in great detail the properties of millions of particles that were formed in the 26-foot-long "aerosol flow tube" at AirUCI.

"What made these findings possible is the ability to characterize multitude of individual particles' properties with high precision," said Zelenyuk. "Incorporating what we found about these particles into models will provide fundamental understanding of formation and transformations of complex organic particles."

This research project represents the initial step towards developing a fundamental, mechanistic theory of organic particle formation and evolution. Future research will proceed to test how general the findings are to other organic particles formed under different conditions from different precursors. In parallel, a fundamental modeling framework that takes the experimental findings into account will be developed.

Explore further: Researcher optimally isolates propylene for commercial use

More information: V Perraud, et al. 2012. "Nonequilibrium atmospheric secondary organic aerosol formation and growth." Proceedings of the National Academy of Science. 109:2836-2841. DOI: 10.1073/pnas.1119909109

Related Stories

Refining atmospheric climate models

Feb 01, 2011

(PhysOrg.com) -- A long, frustrating search for the source of "extra" aerosols seen in field experiments but not in models might have come to an end when scientists at Pacific Northwest National Laboratory ...

Climate sensitivity greater than previously believed

Dec 20, 2011

Many of the particles in the atmosphere are produced by the natural world, and it is possible that plants have in recent decades reduced the effects of the greenhouse gases to which human activity has given rise. One consequence ...

Recommended for you

User comments : 0

Please sign in to add a comment. Registration is free, and takes less than a minute. Read more

Click here to reset your password.
Sign in to get notified via email when new comments are made.