This article has been reviewed according to Science X's editorial process and policies. Editors have highlighted the following attributes while ensuring the content's credibility:

fact-checked

peer-reviewed publication

trusted source

proofread

Study elucidates regulation mechanism for electrocatalytic nitrate reduction

Study elucidates regulation mechanism for electrocatalytic nitrate reduction
The electrocatalytic NO3RR kinetic test and its scale-up for practical applications. Credit: JIN Meng

A research team led by Prof. Zhang Haimin from the Hefei Institutes of Physical Science of the Chinese Academy of Sciences has conducted a systematic study on the regulation mechanism of heterostructure bimetallic phosphide electrocatalysts to improve the performance of electrochemical nitrate reduction reaction.

"The shows different ammonia synthesis performance in different reactors," said Dr. Jin Meng, "so we tried three different electrolyzers to improve the performance of the electrocatalysts."

The configuration of the electrolyzer will greatly affect the local reaction environment near the electrode, and then affect the catalytic performance, the researchers chose three different electrolyzers to study the regulate mechanism of the electrocatalysts performance.

Results were published in Nano Research.

Nitrate anion (NO3-) is significant pollutant in industrial wastewater and agricultural production. Electrocatalytic nitrate reduction (NO3RR) is an effective way to solve and produce green ammonia (NH3). However, the NO3RR process is complex, involving multiple electron and proton transfer, and suffers from low Faraday efficiency due to competition from hydrogen evolution reactions. An electrochemical NO3RR reactor is also crucial for achieving high-efficiency conversion of NO3- to NH3.

Study elucidates regulation mechanism for electrocatalytic nitrate reduction
Theoretical calculations and In-situ spectroscopy characterization toward NO3RR. Credit: JIN Meng

In this study, the researchers synthesized a series of bimetallic copper-nickel phosphide electrocatalysts on commercial carbon paper (CP) by a facile vapor-phase hydrothermal method. The electrocatalytic performance of these catalysts for NO3RR was first evaluated in an H-type electrolytic cell. The results showed that the Cu3P-Ni2P/CP-x could form rich heterointerfaces, which enhanced the and improved the NO3RR efficiency.

To further understand the difference in NO3RR kinetics of electrocatalysts, the researchers used a rotating disk electrode setup to test the corresponding catalytic kinetic parameters.

In addition, they assembled the catalyst into the membrane-electrode-assembly (MEA) electrolyzer, which demonstrated the highly efficient activity and durability for NO3RR at industrial current densities. In-situ spectroscopy characterization, combined with theoretical calculations, revealed that the presence of heterointerfaces effectively regulated the reactant adsorption, and the followed a sequential hydrodeoxygenation pathway.

These results contribute to a better understanding of the electrocatalytic NO3RR process and pave the way for the development of efficient and durable catalysts for sustainable ammonia synthesis.

More information: Meng Jin et al, Heterostructure Cu3P−Ni2P/CP catalyst assembled membrane electrode for high-efficiency electrocatalytic nitrate to ammonia, Nano Research (2024). DOI: 10.1007/s12274-024-6474-z

Journal information: Nano Research

Citation: Study elucidates regulation mechanism for electrocatalytic nitrate reduction (2024, February 29) retrieved 24 May 2024 from https://phys.org/news/2024-02-elucidates-mechanism-electrocatalytic-nitrate-reduction.html
This document is subject to copyright. Apart from any fair dealing for the purpose of private study or research, no part may be reproduced without the written permission. The content is provided for information purposes only.

Explore further

Selenium vacancies regulate d-band centers for upgrading N-containing compounds

1 shares

Feedback to editors