Stress-free path to stress-free metallic films paves the way for next-gen circuitry

Stress-free path to stress-free metallic films paves the way for next-gen circuitry
(top left) An illustration of the HiPIMS process (top right) The energy distribution of tungsten ions arriving at the substrate over time. At short times, there are a large proportion of ions with high energy. (bottom) Stress-free tungsten films created with the selective pulsed bias technique. (a) Plan view transmission electron microscopy (TEM) image of the film; (b) a higher resolution image; (c) reconstructions of the selected area in (b) based on inverse Fourier transforms, with two regions magnified. Credit: Tokyo Metropolitan University

Researchers from Tokyo Metropolitan University have used high power impulse magnetron scattering (HiPIMS) to create thin films of tungsten with unprecedentedly low levels of film stress. By optimizing the timing of a substrate bias pulse with microsecond precision, they minimized impurities and defects to form crystalline films with stresses as low as 0.03 GPa, similar to those achieved through annealing. Their work promises efficient pathways for creating metallic films for the electronics industry.

Modern electronics rely on the intricate, nanoscale deposition of thin metallic films onto surfaces. This is easier said than done; unless done right, film stresses arising from the microscopic internal structure of the film can cause buckling and curving over time. Getting rid of these stresses usually requires heating or annealing. Unfortunately, many of the best metals for the job, e.g., tungsten, have high melting points, meaning that the film needs to be heated to over 1000 degrees Celsius. Not only is this energy intensive, but it severely limits which materials can be used. The race is on to create films out of high melting point metals without these stresses in the first place.

A team led by Associate Professor Tetsuhide Shimizu of Tokyo Metropolitan University has been working with a technique known as high-power impulse magnetron scattering (HiPIMS), a sputtering technique. Sputtering involves applying a across a metallic target and a substrate, creating a plasma of charged which bombards the metallic target and forms a charged vapor; these fly towards the substrate where they form a film. In the case of HiPIMS, the voltage is pulsed in short, powerful bursts. After each pulse, it is known that there is some separation between the arrival of metal and gas ions at the substrate; a synchronized substrate bias pulse can help selectively accelerate the metal ions, creating denser films. Yet despite many efforts, the issue of residual stress remained.

Stress-free path to stress-free metallic films paves the way for next-gen circuitry
Measurements of film stress and lattice properties for films created without a bias (floating), with a continuous bias of 50V, with synchronized pulsed substrate biases (50V, 100V, 200V) using argon as the sputtering gas, and with a synchronized pulsed substrate bias of 50V using krypton as the sputtering gas. FWHM (Full Width at Half Maximum) is a measure of how well ordered the atoms in the films are (the lower the FWHM, the more ordered it is); the lattice parameter is the size of the repeating cells of the crystalline film, with a limit given by the hypothetical "perfectly relaxed" or unstrained crystal. Credit: Tokyo Metropolitan University

Now, using and a tungsten target, the team looked at how ions with different energies arrived at the substrate over time in unprecedented detail. Instead of using a bias pulse set off at the same time as the HiPIMS pulse, they used their knowledge of when different ions arrived and introduced a tiny delay, 60 microseconds, to precisely select for the arrival of high energy metal ions. They found that this minimized the amount of gas ending up in the film and efficiently delivered high levels of kinetic energy. The result was a dense crystalline film with large grains and low film stress. By making the bias stronger, the films became more and more stress-free. The efficient delivery of energy to the film meant that they had, in fact, achieved a similar effect to annealing while they deposited the film. By further swapping out argon for krypton, the team realized films with a stress as low as 0.03 GPa, comparable to what can be made with post-annealing.

Stress-free path to stress-free metallic films paves the way for next-gen circuitry
(a)-(d) show cross-sections of films made using different sputtering gases and pulsed bias voltages, imaged using scanning electron microscopy. Note how the columns (or "grains") get thicker from (a)-(c); similarly thick columns are seen in (d). Credit: Tokyo Metropolitan University

An efficient pathway to -free will have a significant impact on metallization processes and the manufacture of next-generation circuitry. The technology may be applied to other metals and promises big gains for the .

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More information: Tetsuhide Shimizu et al, Low temperature growth of stress-free single phase α-W films using HiPIMS with synchronized pulsed substrate bias, Journal of Applied Physics (2021). DOI: 10.1063/5.0042608
Journal information: Journal of Applied Physics

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Citation: Stress-free path to stress-free metallic films paves the way for next-gen circuitry (2021, July 5) retrieved 28 July 2021 from
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