Dalian Coherent Light Source reveals origin of interstellar disulfur

Dalian Coherent Light Source reveals origin of interstellar medium S2
Researchers directly observed the C + S2 channel in CS2 photodissociation. Credit: LI Zhenxing

Studying the creation and evolution of sulfur-containing compounds in outer space is essential for understanding interstellar chemistry. CS2 is believed to be the most important molecule in comet nuclei, interstellar dust, or ice cores. It could produce CS and S2 fragments after photodissociation.

The International Ultraviolet Explorer satellite only observed the emission spectra of CS and S2, not that of CS2. The photodissociation mechanism of CS2 remains unclear, and S2 fragments have not been experimentally observed before.

Recently, a team led by Prof. Yuan Kaijun from the Dalian Institute of Chemical Physics (DICP) of the Chinese Academy of Sciences (CAS), in cooperation with Prof. Wang Xing'an's group from the University of Science and Technology of China, observed the C+S2 product channel from CS2 photodissociation for the first time using a home-made Time-Sliced Velocity Map Ion Imaging (TS-VMI) experimental setup based on the Dalian Coherent Light Source (DCLS).

The study, published in Journal of Physical Chemistry Letters on Jan. 11, provided direct experimental evidence for the origin of the interstellar medium S2 fragments observed previously.

The researchers investigated the two-photon ultraviolet (UV) and one-photon vacuum ultraviolet (VUV) photodissociation dynamics of CS2 molecules via the VUV free-electron laser (FEL) at DCLS.

They directly observed the C + S2 product channel from CS2 photodissociation and obtained images of the electronically ground/excited states of S2 products with vibrational excitation. The electronically-excited states of the central atom of the CS2 molecule played an important role in the isomerization and photodissociation processes.

This research demonstrated that interstellar medium S2 fragments could be directly generated from CS2 photodissociation.

"Given the similarity of OCS studied in our previous works and CS2 in this work, we believe that the central-atom elimination channel is more general than expected in the of triatomic molecules," said Prof. Yuan.


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More information: Zhenxing Li et al. Direct Observation of the C + S2 Channel in CS2 Photodissociation, The Journal of Physical Chemistry Letters (2021). DOI: 10.1021/acs.jpclett.0c03386
Citation: Dalian Coherent Light Source reveals origin of interstellar disulfur (2021, January 28) retrieved 4 March 2021 from https://phys.org/news/2021-01-dalian-coherent-source-reveals-interstellar.html
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