Dalian Coherent Light Source reveals hydroxyl super rotors from water photochemistry

Dalian Coherent Light Source reveals hydroxyl super rotors from water photochemistry
Hydroxyl super rotors produced from water photochemistry by using Dalian Coherent Light Source, the process of which is ubiquitous in the interstellar space. Credit: YUAN Kaijun

Scientists at the Dalian Institute of Chemical Physics of the Chinese Academy of Sciences recently revealed hydroxyl super rotors from water photochemistry by using the Dalian Coherent Light Source (DCLS). The researchers, under the direction of Prof. Yuan Kaijun and Prof. Yang Xueming, published their findings in Nature Communications.

Hydroxyl (OH) is a key in interstellar oxygen chemistry due to its capacity to react with most gases in the . OH radicals with extraordinarily high rotational levels of excitation were observed by astronomers in emission from HH 211(one of the youngest known stellar outflows) and the T Tauri star DG Tau. It is very unlikely such rotationally hot OH radicals would be formed from any , but they could originate from short wavelength photolysis of H2O. In the present work, the production mechanism of rotationally hot OH radicals was identified by systematic studies of vacuum ultraviolet (VUV) water photochemistry.

"The advent of the intense, pulsed VUV free electron laser at the DCLS opens the way for state-of-the-art molecular photodissociation dynamics studies at any user-selected VUV wavelength," said Yuan.

"Highly rotationally excited OH radicals, so-called 'super rotors' existing above the bond dissociation energy, were observed from the photodissociation of water at 115.2 nm. Such peculiar dissociation dynamics were only observed at around 115.2 nm, which reveals interesting dissociation mechanisms," Yuan added.

The facility provides a chance to investigate the VUV photochemistry of small molecules. The dissociation processes of these molecules are ubiquitous in and should be recognized in appropriate interstellar chemistry models.


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More information: Nature Communications (2019). DOI: 10.1038/s41467-019-09176-z
Journal information: Nature Communications

Citation: Dalian Coherent Light Source reveals hydroxyl super rotors from water photochemistry (2019, March 19) retrieved 24 June 2019 from https://phys.org/news/2019-03-dalian-coherent-source-reveals-hydroxyl.html
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