From hard to soft: Making sponges from mussel shells

From hard to soft: making sponges from mussel shells
Blue mussel shells after initial treatment with acetic acid. Credit: Jennifer Murphy

Scientists have discovered a spongy form of calcium carbonate (CaCO3), a material found in limestone, chalk, marble, and the shells of mussels and other shellfish. While most forms of calcium carbonate are hard minerals, this new form is soft and absorbent. The researchers, reporting November 5 in the journal Matter, made the discovery while exploring new uses for leftover mussel shells.

"The local aquaculture industry here on the east coast of Canada got in touch and told us they were going to start growing more mussels in the ocean and producing more waste, and they asked us if there could be some use for it," says senior author Francesca Kerton, a professor of chemistry at Memorial University Newfoundland. "I hadn't really thought about in nature, so it was really a desire to use a food waste product rather than mining or drilling for minerals."

While there are many industrial applications of calcium carbonate already, the research team discovered this spongey material by accident while exploring ways to make a less-corrosive de-icer for vehicles and roads. When they combined ground up mussel shells with acetic acid—the chemical found in vinegar—a strange, white spongey material emerged in the solution overnight.

"We thought somebody was playing a joke on us, putting bits of filter paper or something into the solution, because it didn't look like anything that we put in there," says Kerton. "So we scooped out some of the material and ran X-ray diffraction on it, and that told us it was calcite."

From hard to soft: making sponges from mussel shells
This photo compares dried and ground mussel shells (left) with the soft calcite material (right). Credit: Jennifer Murphy

Calcite is one of several naturally occurring forms of calcium carbonate. The researchers concluded that the material was formed from extra that didn't react completely with the . They also tested how well the substance could absorb oils and dyes, wondering if it could have applications in marine pollution cleanup. While they found that it was highly absorbent, they have not yet found a practical way to produce enough of the material to be used for large-scale cleaning projects.

From hard to soft: making sponges from mussel shells
The soft calcite material floating in water. Credit: Jennifer Murphy

"We did think it was kind of neat that we could possibly take material from an organism that grows in the sea and treat pollution in the ocean," says Kerton. "The fact that we could absorb oil as well as other materials that have been used was pretty exciting, but the scalability and cost of making this sponge will limit that application."

So, while the researchers do not see this substance cleaning the ocean in the immediate future, that doesn't mean it's useless. The team now hopes to explore that would use much smaller amounts of the material.

"We've got lots of ideas for the future in terms of where it could be used. We're interested in whether it can take up drugs or or help control acid in the body," says Kerton. "Biological medicine might be the area where this is going to make the most impact."

More information: Matter, Kerton et al.: "Hard to Soft: Biogenic Absorbent Sponge-Like Material from Waste Mussel Shells" , DOI: 10.1016/j.matt.2020.09.022

Journal information: Matter

Provided by Cell Press

Citation: From hard to soft: Making sponges from mussel shells (2020, November 5) retrieved 5 February 2023 from
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