February 15, 2019

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Spintronics by 'straintronics': Switching superferromagnetism with electric-field induced strain

The cones represents the magnetization of the nanoparticles. In the absence of electric field (strain-free state) the size and separation between particles leads to a random orientation of their magnetization, known as superparamagnetism Credit: HZB
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The cones represents the magnetization of the nanoparticles. In the absence of electric field (strain-free state) the size and separation between particles leads to a random orientation of their magnetization, known as superparamagnetism Credit: HZB

Switching magnetic domains in magnetic memory normally requires magnetic fields generated by electrical currents, hence requiring large amounts of electrical power. Now, teams from France, Spain and Germany have demonstrated the feasibility of another approach at the nanoscale: "We can induce magnetic order on a small region of our sample by employing a small electric field instead of using magnetic fields," Dr. Sergio Valencia, HZB, says.

The samples consist of a wedge-shaped polycrystalline iron thin film deposited on top of a BaTiO3 substrate. BaTiO3 is a well-known ferroelectric and ferroelastic material: An electric field is able to distort the BaTiO3 lattice and induce mechanical strain. Analysis by revealed that the iron film consists of tiny nanograins (diameter 2,5 nm). At its thin end, the iron film is less than 0.5 nm thick, allowing for low dimensionality of the nanograins. Given their small size, the magnetic moments of the iron nanograins are disordered with respect to each other, this state is known as superparamagnetism.

At the X-PEEM-Beamline at BESSY II, the scientists analysed what happens with the of these nanograins under a small electric field. "With X-PEEM we can map the magnetic order of the iron grains on a microscopic level and observe how their orientation changes while in-situ applying an electric field," says Dr. Ashima Arora, who did most of the experiments during her Ph.D. thesis. Their results show that the electrical field induced a strain on BaTiO3, and this strain was transmitted to the iron nanograins on top of it. Then, formerly superparamagnetic regions of the sample switched to a new state. In this new state, the magnetic moments of the iron grains are all aligned along the same direction, i.e. a collective, long-range ferromagnetic order known as superferromagnetism.

When an electric field is applied, the strain induced on the BaTiO3 substrate is transferred to the nanoparticles forcing their realignment along a common direction, known as superferromagnetism. Credit: HZB
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When an electric field is applied, the strain induced on the BaTiO3 substrate is transferred to the nanoparticles forcing their realignment along a common direction, known as superferromagnetism. Credit: HZB

The experiments were performed at a temperature slightly above room temperature. "This lets us hope that the phenomenon can be used for the design of new composite materials (consisting of ferroelectric and magnetic nanoparticles) for low-power spin-based storage and logic architectures operating at ambient conditions," Valencia says.

Controlling nanoscale magnetic bits in magnetic random access memory devices by electric field-induced strain alone is known as straintronics. It could offer a new, scalable, fast and energy efficient alternative to nowadays magnetic memories.

More information: A. Arora et al, Switching on superferromagnetism, Physical Review Materials (2019). DOI: 10.1103/PhysRevMaterials.3.024403

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