For storing energy from renewable sources, scientists turn to antiferroelectrics

antiferroelectrics
Hysteresis curves showing the electrical properties of antiferroelectric materials. Different colors represent different rare earth element compositions and the four graphs represent different electric field orientations. Credit: Xu et al. Published in Nature Communications

(Phys.org)—One of the greatest challenges in generating energy from renewable sources is finding a way to store the continuously fluctuating energy being produced. Batteries, supercapacitors, and most other energy-storage technologies typically can't respond quickly enough to the second-by-second fluctuations inherent in wind and solar energy sources. One device that does have a sufficiently fast response is electrostatic capacitors, but their drawback is their low energy density—they simply cannot store very much energy in a given volume.

Addressing this problem, researchers in a new study have shown in simulations that antiferroelectric based on bismuth can potentially exhibit very high densities (150 J/cm3), making them a promising candidate material for electrostatic capacitors. The results point to the possibility of a high-performance, environmentally friendly energy-storage device for .

The researchers, Bin Xu and Laurent Bellaiche at the University of Arkansas, and Jorge Íñiguez at the Luxembourg Institute of Science and Technology, have published a paper on their investigation of antiferroelectrics for energy storage in a recent issue of Nature Communications.

"We predict that rare-earth-substituted bismuth ferrite is a very promising system for high-power energy storage due to its high energy densities and good efficiencies, as well as its tuning flexibilities," Xu told Phys.org. "The model we developed connects the storage properties with fundamental energetic properties, which may lead to the discovery of new storage materials based on antiferroelectrics."

The key characteristic of antiferroelectric materials is that their adjacent electric dipoles point in opposite directions, which cancel out and result in a net zero polarization. As a result, the materials become ferroelectric under the application of a sufficiently large electric field. These electric properties can be easily tuned by controlling a variety of parameters.

In the new study, the scientists took advantage of this tunability to increase the energy and efficiency of a particular lead-free antiferroelectric compound (rare-earth-substituted BiFeO3). By changing the orientation of the electric field and the rare earth composition, the researchers predicted the potential for a very high energy density and high efficiency. They expect that tuning other parameters, such as strain or the addition of other rare-earth dopants, may improve these properties even further.

The simulations also enabled the researchers to develop a model to explain the connection between the and the tunable parameters investigated here. This model should also provide guidance for the development of antiferroelectric-based capacitors in the future. The researchers hope that these theoretical results will motivate efforts to experimentally demonstrate antiferroelectric materials with high energy densities.

"With the model, we are interested in assessing the properties of known and hypothetical antiferroelectrics via high-throughput first-principles calculations," Bellaiche said. "The promising candidates will be further examined, in collaboration with experimentalists and other theorists."


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More information: Bin Xu, Jorge Íñiguez, and L. Bellaiche. "Designing lead-free antiferroelectrics for energy storage." Nature Communications. DOI: 10.1038/ncomms15682

Abstract
Dielectric capacitors, although presenting faster charging/discharging rates and better stability compared with supercapacitors or batteries, are limited in applications due to their low energy density. Antiferroelectric (AFE) compounds, however, show great promise due to their atypical polarization-versus-electric field curves. Here we report our first-principles-based theoretical predictions that Bi1−xRxFeO3 systems (R being a lanthanide, Nd in this work) can potentially allow high energy densities (100–150 J cm−3) and efficiencies (80–88%) for electric fields that may be within the range of feasibility upon experimental advances (2–3 MV cm−1). In addition, a simple model is derived to describe the energy density and efficiency of a general AFE material, providing a framework to assess the effect on the storage properties of variations in doping, electric field magnitude and direction, epitaxial strain, temperature and so on, which can facilitate future search of AFE materials for energy storage.

Journal information: Nature Communications

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