Self-healing solar cells 'channel' natural processes
To understand how solar cells heal themselves, look no further than the nearest tree leaf or the back of your hand.
The "branching" vascular channels that circulate life-sustaining nutrients throughout leaves and hands serve as the inspiration for solar cells that can restore themselves efficiently and inexpensively.
In a new paper, North Carolina State University researchers Orlin Velev and Hyung-Jun Koo show that creating solar cell devices with channels that mimic organic vascular systems can effectively reinvigorate solar cells whose performance deteriorates due to degradation by the sun's ultraviolet rays. Solar cells that are based on organic systems hold the potential to be less expensive and more environmentally friendly than silicon-based solar cells, the current industry standard.
The nature-mimicking devices are a type of dye-sensitized solar cells (DSSCs), composed of a water-based gel core, electrodes, and inexpensive, light-sensitive, organic dye molecules that capture light and generate electric current. However, the dye molecules that get "excited" by the sun's rays to produce electricity eventually degrade and lose efficiency, Velev says, and thus need to be replenished to reboot the device's effectiveness in harnessing the power of the sun.
"Organic material in DSSCs tends to degrade, so we looked to nature to solve the problem," Velev said. "We considered how the branched network in a leaf maintains water and nutrient levels throughout the leaf. Our microchannel solar cell design works in a similar way. Photovoltaic cells rendered ineffective by high intensities of ultraviolet rays were regenerated by pumping fresh dye into the channels while cycling the exhausted dye out of the cell. This process restores the device's effectiveness in producing electricity over multiple cycles."
Velev, Invista Professor of Chemical and Biomolecular Engineering at NC State and the lead author of a paper in Scientific Reports describing the research, adds that the new gel-microfluidic cell design was tested against other designs, and that branched channel networks similar to the ones found in nature worked most effectively.
Light-driven degradation of photoactive molecules could be one of the major obstacles to stable long term operation of organic dye-based solar light harvesting devices. One solution to this problem may be mimicking the regeneration functionality of a plant leaf. We report an organic dye photovoltaic system that has been endowed with such microfluidic regeneration functionality. A hydrogel medium with embedded channels allows rapid and uniform supply of photoactive reagents by a convection-diffusion mechanism. A washing-activation cycle enables reliable replacement of the organic component in a dye-sensitized photovoltaic system. Repetitive restoration of photovoltaic performance after intensive device degradation is demonstrated.