Researchers report major advance in using sunlight to produce steam without boiling water
Details of the solar steam method were published online today in ACS Nano. The technology has an overall energy efficiency of 24 percent. Photovoltaic solar panels, by comparison, typically have an overall energy efficiency around 15 percent. However, the inventors of solar steam said they expect the first uses of the new technology will not be for electricity generation but rather for sanitation and water purification in developing countries.
"This is about a lot more than electricity," said LANP Director Naomi Halas, the lead scientist on the project. "With this technology, we are beginning to think about solar thermal power in a completely different way."
The efficiency of solar steam is due to the light-capturing nanoparticles that convert sunlight into heat. When submerged in water and exposed to sunlight, the particles heat up so quickly they instantly vaporize water and create steam. Halas said the solar steam's overall energy efficiency can probably be increased as the technology is refined.
"We're going from heating water on the macro scale to heating it at the nanoscale," Halas said. "Our particles are very small—even smaller than a wavelength of light—which means they have an extremely small surface area to dissipate heat. This intense heating allows us to generate steam locally, right at the surface of the particle, and the idea of generating steam locally is really counterintuitive."
To show just how counterintuitive, Rice graduate student Oara Neumann videotaped a solar steam demonstration in which a test tube of water containing light-activated nanoparticles was submerged into a bath of ice water. Using a lens to concentrate sunlight onto the near-freezing mixture in the tube, Neumann showed she could create steam from nearly frozen water.
Steam is one of the world's most-used industrial fluids. About 90 percent of electricity is produced from steam, and steam is also used to sterilize medical waste and surgical instruments, to prepare food and to purify water.
Most industrial steam is produced in large boilers, and Halas said solar steam's efficiency could allow steam to become economical on a much smaller scale.
People in developing countries will be among the first to see the benefits of solar steam. Rice engineering undergraduates have already created a solar steam-powered autoclave that's capable of sterilizing medical and dental instruments at clinics that lack electricity. Halas also won a Grand Challenges grant from the Bill and Melinda Gates Foundation to create an ultra-small-scale system for treating human waste in areas without sewer systems or electricity.
"Solar steam is remarkable because of its efficiency," said Neumann, the lead co-author on the paper. "It does not require acres of mirrors or solar panels. In fact, the footprint can be very small. For example, the light window in our demonstration autoclave was just a few square centimeters."
Another potential use could be in powering hybrid air-conditioning and heating systems that run off of sunlight during the day and electricity at night. Halas, Neumann and colleagues have also conducted distillation experiments and found that solar steam is about two-and-a-half times more efficient than existing distillation columns.
Halas, the Stanley C. Moore Professor in Electrical and Computer Engineering, professor of physics, professor of chemistry and professor of biomedical engineering, is one of the world's most-cited chemists. Her lab specializes in creating and studying light-activated particles. One of her creations, gold nanoshells, is the subject of several clinical trials for cancer treatment.
For the cancer treatment technology and many other applications, Halas' team chooses particles that interact with just a few wavelengths of light. For the solar steam project, Halas and Neumann set out to design a particle that would interact with the widest possible spectrum of sunlight energy. Their new nanoparticles are activated by both visible sunlight and shorter wavelengths that humans cannot see.
"We're not changing any of the laws of thermodynamics," Halas said. "We're just boiling water in a radically different way."
Solar illumination of broadly absorbing metal or carbon nanoparticles dispersed in a liquid produces vapor without the requirement of heating the fluid volume. When particles are dispersed in water at ambient temperature, energy is directed primarily to vaporization of water into steam, with a much smaller fraction resulting in heating of the fluid. Sunlight-illuminated particles can also drive H2O-ethanol distillation, yielding fractions significantly richer in ethanol content than simple thermal distillation. These phenomena can also enable important compact solar applications such as sterilization of waste and surgical instruments in resource-poor locations.