Carbon nanostructures grow under extreme particle bombardment

Nov 28, 2013
Even at a plasma bombardment that is 10,000 times more intense than the standard production method, carbon nanostructures such as these can develop. Credit: K.Bystrov / DIFFER.

(Phys.org) —Nanostructures, such as graphene and carbon nanotubes, can develop under far extremer plasma conditions than was previously thought. Plasmas (hot, charged gases) are already widely used to produce interesting nanostructures. In the scientific journal Carbon, FOM PhD researcher Kirill Bystrov shows that carbon nanostructures can also develop under far extremer conditions than those normally used for this purpose.

DIFFER's Pilot-PSI device has been built to expose wall materials to plasmas that will rage in future fusion reactors. Such plasmas are 10,000 times more intense than those normally used for the construction of nanomaterials. Using Pilot-PSI, Bystrov's international team demonstrated that this extreme environment provides unexpected possibilities for producing nanostructures.

Out of equilibrium

Plasmas offer major advantages for the controlled production of advanced materials. In the plasma ions and electrons can be brought far out of their thermal equilibria. Under these conditions, the deposition processes can proceed very differently from those at thermal equilibrium. In the widely used technique of plasma-enhanced (PECVD) the plasma density and the quantity of material supplied (carbon) determine which nanostructures develop. The further plasma is from its , the more exotic the structures that develop.

Variation

Even at a plasma bombardment that is 10,000 times more intense than the standard production method, carbon nanostructures such as these can develop. Credit: K.Bystrov / DIFFER.

After they had exposed various materials such as tungsten, molybdenum and graphite to a plasma with a carbon supply, Bystrov's team discovered a layer full of exotic : multi-walled or extra long nanotubes, cauliflower structures and layers of graphene. Varying parameters such as the density, temperature and composition yielded different structures each time. Bystrov: "It was most surprising that an enormous particle bombardment like that which occurs on the edge of a can yield such delicate structures". The influence of the material on which the deposited structures formed was found to be surprisingly small: on all three of the surfaces tested the same types of structures developed.

Versatile machines

In the Pilot-PSI device researchers can expose materials to extreme conditions, such as those that will prevail at the wall of future fusion reactors. Credit: DIFFER.

With the research, Bystrov and his colleagues do not yet have a competitor for the PECVD technique. "Our interest is in demonstrating that you can allow interesting processes to occur in environments 10,000 times more intense than you would expect," Bystrov writes in his publication. Research leader dr. Greg De Temmerman from the Plasma Surface Interactions team at DIFFER: "We set up these experiments to investigate what happens with the wall materials in future fusion reactors. This research demonstrates that the conditions in Pilot-PSI and its big brother Magnum-PSI are also interesting far outside the fusion community. These are highly versatile machines."

Explore further: Unexpected energy barrier for uptake of hydrogen in tungsten wall of fusion reactor

More information: Spontaneous synthesis of carbon nanowalls, nanotubes and nanotips using high flux density plasmas, Carbon, 28 November 2013. DOI: 10.1016/j.carbon.2013.11.051

Related Stories

Hot lithium vapors shield fusion facility walls

Nov 13, 2013

Recent experiments provide the first assessment of the toughness of a novel lithium coating in the face of intense bombardment by very hot plasma in the divertor region of fusion devices. The results show ...

Lifting fusion power onto an (optimized) pedestal

Nov 13, 2013

In a collaborative effort, researchers in the United States and the United Kingdom have developed a new technique that will help them optimize the transport barrier, or pedestal, in fusion plasmas, which ...

Recommended for you

New absorber will lead to better biosensors

2 hours ago

Biological sensors, or biosensors, are like technological canaries in the coalmine. By converting a biological response into an optical or electrical signal, they can alert us to dangers in our external and internal environments. ...

Ultrafast remote switching of light emission

22 hours ago

Researchers from Eindhoven University of Technology can now for the first time remotely control a miniature light source at timescales of 200 trillionth of a second. They published the results on Sept. 2014 ...

Nanotube cathode beats large, pricey laser

Sep 30, 2014

Scientists are a step closer to building an intense electron beam source without a laser. Using the High-Brightness Electron Source Lab at DOE's Fermi National Accelerator Laboratory, a team led by scientist ...

User comments : 1

Adjust slider to filter visible comments by rank

Display comments: newest first

ViperSRT3g
not rated yet Jan 28, 2014
I'm not entirely familiar with the whole fusion process that we still seem to be tinkering with thus far. But where would all of this carbon plasma be coming from in a fusion reactor? Do they fuse enough materials that we end up spouting carbon from within a reactor?