Protons hop from one water molecule to another given suitable energy conditions

July 23, 2013
Model of a hydrogen bridge bond network in liquid water

Protons, as positively charged hydrogen ions, move very rapidly in water from one water molecule to the next, which is why the conductivity of water is relatively high. The principle of proton conduction in water has been known for 200 years and is named the Grotthuss mechanism after its discoverer, Theodor Grotthuss. It is based on the assumption that it is not that a single specific proton moving from one molecule to another; instead, there is cleavage of bonds.

One proton docks onto a molecule and this causes another proton to leave that molecule and bind to another molecule somewhere else. This mechanism has been compared to a 'bucket line' to explain the rapid diffusion of the individual protons. However, this concept oversimplifies the situation and belies the complexity of the structure of water.

Researchers from Zurich and Mainz have now been able to analyze the mechanism in more detail using theoretical calculations and have shown that the currently accepted picture of proton diffusion may need to be revised. "The simulation shows that the crossover from one water molecule to the next occurs more quickly than previously thought and then there is a rest period until the next crossover," said Professor Thomas D. Kühne of the Institute of Physical Chemistry at Johannes Gutenberg University Mainz (JGU), describing the results. These were published online on July 18, 2013 in the journal Proceedings of the National Academy of Sciences.

"We show that the diffusion of protons and hydroxide ions occurs during periods of intense activity involving concerted proton hopping, followed by periods of rest," wrote primary author Ali A. Hassanali of the Swiss Federal Institute of Technology Zurich in the publication. In the model of proton diffusion that researchers have now developed, the hydrogen bridge network is equivalent to an aggregation of closed rings. The resulting proton chains serve as a 'road' in the hydrogen bridge network that make possible long proton jumps across multiple hydrogen bridge bond formations. "The 'dance' around each other until they achieve an energetically favorable status. Only then will a proton hop along the 'road' to another molecule," explained Kühne. As a result, there is temporary formation of protonated water molecules with three protons.

In addition to the relevance of transfer in aqueous systems, the results may also be applicable to important biological systems such as enzymes and macromolecules.

Explore further: Chemists explain the molecular workings of promising fuel cell electrolyte

More information: PNAS, 18. Juli 2013 DOI:10.1073/pnas.1306642110

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not rated yet Jul 23, 2013
Pure water is not a conductor. I remember a test for water purifiers a friend was selling was to test the conductivity before and after purification ~ conduction drops dramatically.

See Wikipedia:
"Pure water has a low electrical conductivity, "

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