Highlight: Quasi-Crystalline Order at Nanoscale

January 11, 2010
TEM showing the two-dimensional dodecagonal quasi-crystalline structure self-assembled from 5-nm Au and 13.4-nm Fe3O4 nanoparticles.

Nanoparticles have a strong tendency to form periodic structures. Mixing and matching of two different types of nanoparticles allows the formation of binary nanoparticle superlattices isostructural to ionic or intermetallic compounds. In addition to periodic superlattices, binary mixtures of nearly spherical nanoparticles could lead to the growth of quasi-crystals.

CNM staff in the Nanobio Interfaces Group, together with colleagues from the University of Chicago and the University of Pennsylvania, have found that two-dimensional dodecagonal quasi-crystals can be formed in mixtures of 3-nm Pd and 9-nm PbS, 5-nm Au and 13.4-nm Fe2O3, and 4.7-nm Au and 12.6-nm Fe3O4 .

Studies of of quasi-crystalline nanoparticle superstructures will provide insight into the formation of the quasi-crystalline phase in atomic systems. The assembly of the dodecagonal quasi-crystalline phase from different nanoparticle combinations shows that quasi-crystalline ordering can be a quite common phenomenon in nanocrystal solids.

Explore further: DNA technique yields 3-D crystalline organization of nanoparticles

More information: "Quasi-crystalline order in self-assembled binary nanoparticle superlattices," D. V. Talapin, E. V. Shevchenko, M. I. Bodnarchuk, X. Ye, J. Chen, and C. B. Murray, Nature 461, 964-967 (15 October 2009), doi:10.1038/nature08439

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