Arrays of metallic nanoparticles can form an optical cavity tunable by liquid crystals

Arrays of metallic nanoparticles can form an optical cavity tunable by liquid crystals
FIG. 1. (a) Schematic representation of the device with planar LC. The device consists of a glass substrate coated with ITO with a nanoparticle array fabricated on top and covered by a PS alignment layer. The LC layer is held in place on top of the PS by a second glass substrate coated with ITO and a PI alignment layer. The rubbing directions of the alignment layers are indicated by the orange double headed arrows. The extraordinary optical axis is parallel to the LC alignment, which is in this case along the y axis. (b) Schematic representation of the same device under application of an electric potential and displaying a homeotropic LC. (c) Photograph of two devices shown as the two squares of arrays with different nanorod sizes but equal array pitches. The angle at which the photo was taken allowed for the diffraction of blue wavelengths to enter the camera, hence the color of the particle arrays. (d) Scanning electron microscope image of the particle array with nanorod dimensions

The manuscript "Electric tuning and switching of the resonant response of nanoparticle arrays with liquid crystals" by Erik van Heijst and co-workers (PSN) has been selected as featured article and journal cover in the last issue of the Journal of Applied Physics and a SciLight article has been written by the American Institute of Physics. In this article, it is shown how collective plasmonic resonances can be electrically controlled with liquid crystals. This is the first manuscript of the EHCI and ICMS together. Erik van Heijst did his work as part of his graduation research in the Applied Physics and Chemical Engineering department where he obtained the double degree last year.

Plasmonic resonances in have shown promise for a wide range of applications, including nanolasers and extremely sensitive nano-sized biosensors. The field of plasmonics has seen steady improvements toward active control over resonances using the refractive index of the material between .

Van Heijst et al. designed, constructed and analyzed a tunable device combining nano-particle arrays that support collective surface lattice resonances (SLRs) with liquid crystals. By leveraging the tunability of liquid crystals and the effect of the refractive index of the environment on SLRs, the optical response of the array can be controlled electrically by switching between states in the liquid crystal. The resulting rapid and reversible spectral tuning gives users a large degree of control over SLR wavelength.

Narrow collective resonances within arrays are key features in the device's ability to tune resonance with such control.

"Because we have narrow collective resonances, then the changes in refractive index that we can induce with the liquid crystal are sufficient to shift the resonance almost its full width," said author Jaime Gómez Rivas.

Despite being delocalized with respect to the individual nanoparticles, the hybrid plasmonic-photonic modes of SLRs exhibit large enhancements of the electric field intensity.

Experimentally, the group found the SLR energy shift was less than what was indicated in simulations, which they attribute to the rough surface of the indium tin oxide electrodes and the imperfect alignment of liquid crystals imposed by the nanoparticle structure.

The group aims to tune the emission of molecules dispersed in the , which could then be coupled to the collective and ultimately allow a change in crystal orientation.

More information: Erik A. P. van Heijst et al, Electric tuning and switching of the resonant response of nanoparticle arrays with liquid crystals, Journal of Applied Physics (2022). DOI: 10.1063/5.0079016

Journal information: Journal of Applied Physics

Citation: Arrays of metallic nanoparticles can form an optical cavity tunable by liquid crystals (2022, March 2) retrieved 24 July 2024 from
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