Protector against air pollution is vulnerable to air
Catalyst research aims to make gasoline less polluting. It turns out that during experiments, it is actually necessary to protect catalysts from the air itself.
Thanks to catalysts, gasoline produces much less pollution today. Crude oil contains sulfur, which refineries filter out in the process of turning oil into gasoline. To do this, they add hydrogen and such catalysts as NiMoS2. The hydrogen removes a sulfur component of NiMoS2, giving the catalyst room to collect the sulfur from the oil.
To further improve the process, scientists research substances like NiMoS2. A small adaptation in the chemical composition could make it a more efficient catalyst. In such experiments, it is important to know how to keep the studied sample free from external influences.
A group of physicists led by Joost Frenken (Leiden University) and Patricia Kooyman (University of Cape Town) together with TU Eindhoven have now shown that exposure to air is very harmful. "Oxygen molecules from the air oxidize the NiMoS2 catalyst particles, so that further studying the sample essentially produces no relevant information," says first author Marien Bremmer. "We noticed that the oxidation occurred extremely fast at first, but slowed down in the long-term. This indicates the formation of a shielding oxide ring."
The research group used a high-resolution transmission electron microscope (HRTEM) to observe that after only 24 hours, 20 percent of each NiMoS2 particle is covered with oxygen. They describe the study in pubs.acs.org/doi/abs/10.1021/acs.jpcc.6b06030" rel="nofollow" target="_blank">the Journal of Physical Chemistry C.