Chemical synthesis of a powerful, high-energy compound

July 20, 2016, Wiley
Chemical synthesis of a powerful, high-energy compound
Credit: Angewandte Chemie

Trinitrotoluene or TNT has been considered as the standard measure for explosives for 100 years, although new high-energy-density materials or HEDMs outperform this substance in terms of explosion power, safety, but also environmental compatibility. In the journal Angewandte Chemie, Russian scientists present the synthesis of a highly interesting HEDM, which exhibits excellent energetic properties as well as a beautiful, butterfly-like structure.

Besides the pure performance aspect, research on new explosives has focused on finding substances that are less toxic to the environment, and less sensitive and thus more safe, but still have high explosive power. Both the environmental aspect and explosiveness can be addressed by designing with high nitrogen content but low carbon content, because nitrogen-rich substances decompose mainly into environmentally benign pure nitrogen, avoiding the formation of toxic nitrosamines. On the other hand, introducing a cyclic electron delocalization and alternating ionic charges in the molecule will add thermostability and high density. A research team led by Aleksandr M. Churakov from the Russian Academy of Sciences, Moscow, has long studied the very promising compound TTTO, which was theoretically calculated to combine very favorable parameters. They have now achieved its synthesis.

TTTO is a completely symmetric compound composed of a bicyclic aromatic ring system. Eight of the ten atoms of the bicycle are nitrogen so that the double ring system comprises two fused tetrazine rings in a butterfly-like arrangement. The oxidation of two of the four nitrogen atoms in each tetrazine ring with one oxygen atom, respectively, provides perfect oxygen balance and additional structural stabilization. Thus, this compound will decompose in just pure nitrogen and carbon dioxide, and in addition, it is assumed to have excellent energetic characteristics.

Of course, the synthesis of explosives needs great care. In the case of TTTO, the scientists developed a procedure involving ten steps. Having the new compound in hand, they start to characterize it to check if the theoretical properties are fulfilled. One of the critical practical requirements its sensitivity to thermal or mechanical treatment. "In the preliminary experiments, it did not detonate when rubbed in an agate mortar, but exploded in unglazed porcelain one," the authors wrote on their initial studies. Another requirement of new energetic materials is water resistance. In that respect, the authors admit that TTTO may be a bit weak. On the other hand, the chemical and energetic performances of new nitrogen-rich highly energetic compounds have to be carefully balanced. Therefore, TTTO serves as a particularly valid example of next-generation high-energy-density materials, which clearly outperform the traditional TNT standard.

Explore further: New explosives provide enhanced safety, high energy

More information: Michael S. Klenov et al. Synthesis of Tetrazino-tetrazine 1,3,6,8-Tetraoxide (TTTO), Angewandte Chemie International Edition (2016). DOI: 10.1002/anie.201605611

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TheGhostofOtto1923
3.7 / 5 (3) Jul 20, 2016
The holy grail - a chemical reaction with power sufficient to initiate fusion.

"Samuel T. Cohen, the "father of the neutron bomb", claimed for some time that red mercury is a powerful explosive-like chemical known as a ballotechnic. The energy released during its reaction is allegedly enough to directly compress the secondary without the need for a fission primary in a thermonuclear weapon. He claimed that he learned that the Soviet scientists perfected the use of red mercury and used it to produce a number of softball-sized pure fusion bombs weighing as little as 10 lb (4.5 kg), which he claimed were made in large numbers."

-Hokey but intriguing.

Ever wonder why the cold war was a hoax? Because the existence of nuclear weapons meant that they could be smuggled and planted anywhere in the world and detonated at will.

The fact that this was possible meant that if the soviets and the west were true enemies then a war would already have occurred.
KBK
5 / 5 (1) Jul 20, 2016
In a directly related and connected aspect...check out the work of Professor Nagaoka, who was the most respected scientist in Japan.

He used electric arcs fired through a mix of tungsten powder and mercury, to transmute the tungsten mercury mixture into containing minute amounts of gold:

http://www.slides...-27-2013

Mitsubishi Heavy industries and Toyota Corporation back that up with filed for and granted patents on transmutation of elements.

Specific details on all aspects are at the supplied link.
rgw
5 / 5 (1) Jul 23, 2016
>>>>TheGhostofOtto1923

You forgot to reveal that Red mercury was brought to Earth by the Reptilian
Galactic Overlords to power the Photon weapons installed in the Pyramid of Cheops to repulse the attack of 6th Dimensional Brain Eaters.

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