Revolutionary solar-friendly form of silicon shines

November 17, 2014, Carnegie Institution for Science
View through the channels of Si24. This new zeolite-type allotrope of silicon (isotypic with the zeolite CAS) has an open framework comprised of 5-, 6- and 8-membered sp3-bonded silicon rings. Credit: Timothy Strobel

Silicon is the second most-abundant element in the earth's crust. When purified, it takes on a diamond structure, which is essential to modern electronic devices—carbon is to biology as silicon is to technology. A team of Carnegie scientists led by Timothy Strobel has synthesized an entirely new form of silicon, one that promises even greater future applications. Their work is published in Nature Materials.

Although silicon is incredibly common in today's technology, its so-called indirect band gap semiconducting properties prevent it from being considered for next-generation, high-efficiency applications such as light-emitting diodes, higher-performance transistors and certain photovoltaic devices.

Metallic substances conduct electrical current easily, whereas insulating (non-metallic) conduct no current at all. Semiconducting materials exhibit mid-range electrical conductivity. When are subjected to an input of a specific energy, bound electrons can move to higher-energy, conducting states. The specific energy required to make this jump to the conducting state is defined as the "band gap." While direct band gap materials can effectively absorb and emit light, indirect band gap materials, like diamond-structured silicon, cannot.

In order for silicon to be more attractive for use in new technology, its indirect band gap needed to be altered. Strobel and his team—Carnegie's Duck Young Kim, Stevce Stefanoski and Oleksandr Kurakevych (now at Sorbonne) —were able to synthesize a new form of silicon with a quasi-direct band gap that falls within the desired range for solar absorption, something that has never before been achieved.

The silicon they created is a so-called , which means a different physical form of the same element, in the same way that diamonds and graphite are both forms of carbon. Unlike the conventional diamond structure, this new silicon allotrope consists of an interesting open framework, called a zeolite-type structure, which is comprised of channels with five-, six- and eight-membered silicon rings.

The new Si24 allotrope has an open-framework structure comprised of 5-, 6- and 8-membered sp3-bonded silicon rings. Small atoms like sodium (yellow) amd lithium (green), and potentially molecules like water, can readily diffuse through these channels, with potential applications spanning electrical energy storage and molecular-scale filtering. Credit: Duck Young Kim

They created it using a novel high-pressure precursor process. First, a compound of silicon and sodium, Na4Si24, was formed under high-pressure conditions. Next, this compound was recovered to ambient pressure, and the sodium was completely removed by heating under vacuum. The resulting pure silicon allotrope, Si24, has the ideal for solar energy conversion technology, and can absorb, and potentially emit, light far more effectively than conventional diamond-structured silicon. Si24 is stable at ambient pressure to at least 842 degrees Fahrenheit (450 degrees Celsius).

"High-pressure precursor synthesis represents an entirely new frontier in novel energy materials," remarked Strobel. "Using the unique tool of high pressure, we can access novel structures with real potential to solve standing materials challenges. Here we demonstrate previously unknown properties for , but our methodology is readily extendible to entirely different classes of materials. These new structures remain stable at atmospheric pressure, so larger-volume scaling strategies may be entirely possible."

"This is an excellent example of experimental and theoretical collaboration," said Kim. "Advanced electronic structure theory and experiment have converged to deliver a real material with exciting prospects. We believe that high-pressure research can be used to address current energy challenges, and we are now extending this work to different materials with equally exciting properties."

The new Si24 allotrope has an open-framework structure comprised of 5-, 6- and 8-membered sp3-bonded silicon rings. Credit: Duck Young Kim

Explore further: Solar cell compound probed under pressure

More information: Synthesis of an open-framework allotrope of silicon, Nature Materials, DOI: 10.1038/nmat4140

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1 / 5 (1) Nov 17, 2014
Better PV means less pollution from carbon fuels.
5 / 5 (3) Nov 17, 2014
This almost sounds like a process reasonably scalable in industry. One hopes it can be.
3 / 5 (2) Nov 17, 2014
also: Physorg: the doi link is broken to get to the source article.
not rated yet Nov 17, 2014
It'll get you 20% of the way there no matter how revolutionary it is. But hey, 20% isn't bad at all.
1 / 5 (1) Nov 17, 2014
The doi link works fine. These are the first 4 lines:
"Silicon is ubiquitous in contemporary technology. The most stable form of ​silicon at ambient conditions takes on the structure of diamond (cF8, d-Si) and is an indirect bandgap semiconductor, which prevents it from being considered as a next-generation platform for semiconductor technologies"

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