Copper nanowires offer an efficient, inexpensive approach to solar energy harvesting

November 22, 2013
This image shows a network of copper nanowires. Credit: Zuofeng Chen

Copper adorns the Statue of Liberty, makes sturdy, affordable wiring, and helps our bodies absorb iron. Now, researchers at Duke University would like to use copper to transform sunlight and water into a chemical fuel.

Converting solar energy into storable fuel remains one of the greatest challenges of modern chemistry. One of the ways chemists have tried to capture the power of the sun is through water splitting, in which the atoms of H2O are broken apart so the hydrogen may be collected and used as fuel. Plants do this naturally through photosynthesis, and for half a century, scientists have tried to recreate that process by tinkering with chemical catalysts jumpstarted by sunlight.

Indium tin oxide (ITO) is one material they've commonly tried to use. Researchers prefer it for its transparency—which allows sunlight to pass through and trigger the water-splitting reactions—and its ability to conduct electricity. But ITO is far from an ideal material.

"Indium is not very abundant," said Ben Wiley, assistant professor of chemistry at Duke University. "It is similar in abundance to silver in the earth's crust." As a result, solar fuel cells using ITO will likely remain expensive and uncompetitive with conventional energy sources like coal and natural gas, he said.

Wiley's lab has created something they hope can replace ITO: copper nanowires fused in a see-through film. The team—including two postdoctoral researchers, a graduate student, and a former graduate student from Duke—published their new approach last month in the chemistry journal Angewandte Chemie.

The copper nanowires, seen here with a nickel coating, can split water molecules under the power of sunlight. Credit: Zuofeng Chen

Copper is 1000 times more plentiful and 100 times less expensive than indium. Copper nanowire catalysts also cost less to produce than their ITO counterparts because they can be "printed" on pieces of glass or plastic in a liquid ink form, using a machine that functions much like a printing press. ITO production, by contrast, requires large, sequential chambers of pumps and vacuums that deposit a thin layer of indium atoms at a far slower rate.

The copper nanowire films consist of networks of microscopic metal rods, the properties and applications of which Wiley's lab has studied for years. The nanowires provide a for catalyzing chemistry, and Wiley's team experimented with coating them in either cobalt or nickel—metals that serve as the actual chemical catalyst. Even with a coat of cobalt or nickel, the nanowire films allow nearly seven times more sunlight to pass through than ITO. The films are also flexible, leading Wiley to imagine the completed fuel cells one day being attached to backpacks or cars.

In the meantime, engineering and chemistry challenges remain. The nanowire films carry out only one half of the water-splitting equation, a process called water oxidation. The other half of the reaction involves using the electrons obtained from water oxidation to reduce water to hydrogen. Wiley's team expects to publish their work on this process in the coming year.

This is a close-up of a single copper nanowire and its nickel shell. Credit: Zuofeng Chen

"A lot of groups are working on putting together complete devices to generate fuels from sunlight," he said, but "the efficiencies and costs of these systems have to be improved for them to get to commercial [production]."

Wiley noted that production is just one application of the nanowire films they study. The nanowires also show promise for use in flexible touch screens, organic LED (or OLED) lights and smart glass.

Explore further: More transparency: Optically transparent water oxidation catalyst made from copper nanowires

More information: "Optically Transparent Water Oxidation Catalysts Based on Copper Nanowires," Zuofeng Chen, Aaron Rathmell, Shengrong Ye, Adria Wilson, Ben Wiley. Angewandte Chemie, October 18, 2013. 10.1002/ange.201306585

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Faux Science Slayer
not rated yet Dec 02, 2013
What is unmentioned is that water is a great solvent and to prevent contamination in micro systems would require Reverse Osmosis grade feedstock. Also catalysts do have erosion life cycle and nano catalysts likely have a very short service life. Hydrogen is a low density energy in combustion or in direct fuel cell applications. Possible that this could be a closed loop water cycle, but like most 'sustainable' schemes, does not appear to be a practical technology.

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