Neutron analysis explains dynamics behind best thermoelectric materials

Neutron analysis explains dynamics behind best thermoelectric materials
Neutron scattering experiments performed at ORNL show that lead telluride exhibits a strong anharmonic coupling between its optical and acoustic lattice vibrations, with a drop in thermal conductivity resembling a waterfall in this data image. This newly discovered coupling helps explain the low thermal conductivity that makes lead telluride a promising material for thermoelectric devices. Credit: ORNL

Neutron analysis of the atomic dynamics behind thermal conductivity is helping scientists at the Department of Energy's Oak Ridge National Laboratory gain a deeper understanding of how thermoelectric materials work. The analysis could spur the development of a broader range of products with the capability to transform heat to electricity.

Researchers performed experiments at both of ORNL's neutron facilities -- the and the -- to learn why the material lead telluride, which has a similar molecular structure to common table salt, has very low thermal conductivity, or heat loss -- a property that makes lead telluride a compelling thermoelectric material.

"The microscopic origin of the low thermal conductivity is not well understood. Once we do understand it better we can design materials that perform better at converting heat to electricity," said Olivier Delaire, a researcher and Clifford Shull Fellow in ORNL's Neutron Sciences Directorate.

Delaire's research, reported in , shows that an unusual coupling of microscopic vibrational modes, called phonons, is responsible for the disruption of the dynamics that transport the thermal energy in lead telluride.

In typical , which have a lattice-like atomic structure, the conduction of heat is enhanced by the propagation of phonons along the lattice. The atoms conduct heat by vibrating in a chain, similar to vibrations propagating along a spring.

Delaire's team determined through analysis at the SNS that lead telluride, although having the same as rock salt, exhibits a strong coupling of phonons, which results in a disruption of the lattice effect and cancels the ability to conduct heat.

"The resolution of the SNS's Cold Neutron Chopper Spectrometer, along with the high flux, have been quite important to making these time of flight measurements," Delaire said.

By controlling in thermoelectrics, less energy is dispersed and more heat can be directed to power generation. Today, thermoelectric materials are used to power the deep-space probes that explore the outer planets and solar system. Cruising beyond the range of solar collectors, the crafts' reactor thermoelectric generators use heat from decaying radioisotopes to generate power.

New, advanced thermoelectric materials could be used to develop more earthly applications, such as vehicle exhaust systems that convert exhaust heat into electricity, reducing the need for alternators. New could also help concentrate solar energy for power generation and recover waste heat for industrial processes.

Delaire's team performed additional neutron measurements with HFIR's triple-axis spectrometer. Data analysis has been facilitated through collaboration with ORNL's Materials Theory group. Samples were synthesized and characterized in ORNL's Correlated Electrons Materials group.


Explore further

Thermoelectric materials: recycling energy

Citation: Neutron analysis explains dynamics behind best thermoelectric materials (2011, June 6) retrieved 23 September 2019 from https://phys.org/news/2011-06-neutron-analysis-dynamics-thermoelectric-materials.html
This document is subject to copyright. Apart from any fair dealing for the purpose of private study or research, no part may be reproduced without the written permission. The content is provided for information purposes only.
0 shares

Feedback to editors

User comments

Please sign in to add a comment. Registration is free, and takes less than a minute. Read more