High-temperature superconductor spills secret: A new phase of matter

March 24, 2011
An unprecedented three-pronged study has found that one type of high-temperature superconductor may exhibit a new phase of matter. As in all superconductors, electrons pair off (bottom) to conduct electricity with no resistance when the material is cooled below a certain temperature. But in this particular copper-based superconductor, many of the electrons in the material don’t pair off; instead they form a distinct, elusive order (orange plumes) that had not been seen before. Scientists at SLAC National Accelerator Laboratory, Stanford University, Lawrence Berkeley National Laboratory and institutions in Japan and Thailand report their findings in the March 25 issue of Science. Credit: Greg Stewart/SLAC

(PhysOrg.com) -- Scientists from the U.S. Department of Energy's Lawrence Berkeley National Laboratory (Berkeley Lab) and the University of California at Berkeley have joined with researchers at Stanford University and the SLAC National Accelerator Laboratory to mount a three-pronged attack on one of the most obstinate puzzles in materials sciences: what is the pseudogap?

A collaboration organized by Zhi-Xun Shen, a member of the Stanford Institute for Materials and Energy Science (SIMES) at SLAC and a professor of physics at Stanford University, used three complementary experimental approaches to investigate a single material, the high-temperature superconductor Pb-Bi2201 (lead bismuth strontium lanthanum copper-oxide). Their results are the strongest evidence yet that the pseudogap phase, a mysterious electronic state peculiar to high-temperature superconductors, is not a gradual transition to superconductivity in these materials, as many have long believed. It is in fact a distinct phase of matter.

"This is a paradigm shift in the way we understand high-temperature superconductivity," says Ruihua He, lead author with Makoto Hashimoto of the paper in the March 25 issue of the journal Science that describes the team's findings. "The involvement of an additional phase, once fully understood, might open up new possibilities for achieving superconductivity at even higher temperatures in these materials." When the research was done Hashimoto and He were members of SIMES, of Stanford's Department of Applied Physics, and of Berkeley Lab's Advanced Light Source (ALS), where He is now a postdoctoral fellow.

The pseudogap mystery

Superconductivity is the total absence of resistance to the flow of electric current. Discovered in 1911, it was long thought to occur only in metals and only below a critical temperature (Tc) not far above absolute zero. "Ordinary" superconductivity commonly takes place at 30 kelvins (30 K) or less, equivalent to more than 400 degrees below zero Fahrenheit. Awkward as reaching such low temperatures may be, ordinary superconductivity is widely exploited in industry, health, and science.

High-Tc superconductors were discovered in 1986. "High" is a relative term; the highest-Tc superconductors function at temperatures five times higher than ordinary superconductors but still only about twice that of liquid nitrogen. Many high-Tc superconductors have been found, but the record holders for critical temperature remain the kind first discovered, the cuprates — brittle oxides whose structure includes layers of copper and oxygen atoms where current flows.

In this phase diagram common to many cuprate superconductors, the insulating phase typical of undoped cuprate compounds appears at the far left (black). Other phases appear with increased hole doping -- the dome-shaped superconducting phase below Tc (blue), the mysterious pseudogap below T* (red), and a “normal metallic” phase (white). New evidence from studies of Bi2201 (crystal structure inset) along the temperature range shown in greeen strongly supports the idea that the pseudogap is in fact a distinct phase of matter that persists into the superconducting phase. If so the T* phase transition must terminate in a quantum critical point (Xc) at zero temperature. Credit: Ruihua He, Lawrence Berkeley National Laboratory

In all known superconductors electrons join in pairs (Cooper pairs) to move in correlated fashion through the material. It takes a certain amount of energy to break Cooper pairs apart; in ordinary superconductors, the absence of single-electron states below this energy constitutes a superconducting gap, which vanishes when the temperature rises above Tc. Once in the normal state the electrons revert to unpaired, uncorrelated behavior.

Not so for cuprate superconductors. A similar superconducting gap exists below Tc, but when superconductivity ceases at Tc the gap doesn't close. A "pseudogap" persists and doesn't go away until the material reaches a higher temperature, designated T* (T-star). The existence of a pseudogap in the normal state is itself anything but normal; its nature has been heatedly debated ever since it was identified in cuprates more than 15 years ago.

Attempts to explain what's going on in the pseudogap have coalesced around two main schools of thought. Traditional thinking holds that the pseudogap represents a foreshadowing of the superconducting phase. As the temperature is lowered, first reaching T*, a few electron pairs start to form, but they are sparse and lack the long-range coherence necessary for superconductivity — they can't "talk" to one another. As the temperature continues to fall, more such pairs are formed until, upon reaching Tc, virtually all conducting electrons are paired and act in correlation; they're all talking. In this scheme, there's only a single phase transition, which occurs at Tc.

Another school of thought argues that the appearance of the pseudogap at T* is also a true phase transition. The pseudogap does not represent a smooth shift to the superconducting state but is itself a state distinct from both superconductivity and normal "metallicity" (the usual state of delocalized, uncorrelated electrons). This new phase implies the existence of a "quantum critical point" — a point along a line at zero temperature where competing phases meet. In theory, with competing phases wildly fluctuating in the neighborhood of a quantum critical point, there may be entirely new routes to superconductivity.

"Promising as the 'quantum critical' paradigm is for explaining a wide range of exotic materials, high-Tc superconductivity in cuprates has stubbornly refused to fit the mold," says Joseph Orenstein of Berkeley Lab's Materials Sciences Division, a professor in physics at UC Berkeley, whose group conducted one of the research team's three experiments. "For 20 years, the cuprates managed to conceal any evidence of a phase-transition line where the quantum critical point is supposed to be found."

In recent years, however, hints have emerged. "New ultrasensitive probes have found fingerprints of phase transitions in high-Tc materials," Orenstein says, "although there's been no smoking gun. The burning question is whether we can discover the nature of the new phase or phases."

A multipronged attack on the pseudogap

In the Stanford-Berkeley study, three groups of researchers joined forces to probe the pseudogap phase on the same sample.

"Pb-Bi2201 was chosen because, first, it is structurally simple, and second, it has a relatively wide temperature range between Tc and T*," says Ruihua He. "This permits a clean separation of any remnant effect of superconductivity from genuine pseudogap physics."

Groups led by Z.-X. Shen at beamline 5‑4 of the Stanford Synchrotron Radiation Lightsource (SSRL) at SLAC and by Zahid Hussain, ALS Division Deputy for Scientific Support, at beamline 10.0.1 of Berkeley Lab's ALS, studied the sample with angle-resolved photoemission spectroscopy (ARPES). In ARPES, a beam of x-rays directed at the sample surface excites the emission of valence electrons. By monitoring the kinetic energy and momentum of the emitted electrons over a wide temperature range the researchers map out the material's low-energy electronic band structure, which determines much of its electrical and magnetic properties.

At Stanford, researchers led by Aharon Kapitulnik of SIMES, a professor in applied physics at Stanford University, studied the same crystal of Pb-Bi2201 with the magneto-optical Kerr effect. In light reflected from the sample under a zero magnetic field, tiny rotations of the plane of polarization are measured as the temperature changes. The rotations are proportional to the net magnetization of the sample at different temperatures.

Finally, Orenstein's group at Berkeley applied time-resolved reflectivity to the sample. A pump pulse from a laser excites electrons many layers of atoms deep, temporarily affecting the sample's reflectivity. Probe pulses, timed to follow less than a trillionth of a second after the pump pulses, reveal changes in reflection at different temperatures.

All these experimental techniques had previously pointed to the possibility of a phase transition in the neighborhood of T* in different cuprate materials. But no single result was strong enough to stand alone.

ARPES experiments performed in 2010 by the same group of experimenters as in the present study revealed the abrupt opening of the pseudogap at T* in Pb-Bi2201. Variations in T* in different materials and even different samples, as well as in the surface conditions to which ARPES is sensitive, had left room for uncertainty, however.

In 2008, the Kerr effect was measured in another cuprate, also by the same group as in the present study, and showed a change in magnetization from zero to finite across T*. This was long-sought thermodynamic evidence for the existence of a phase transition at T*. But compared to the pronounced spectral change seen by ARPES, the extreme weakness of the Kerr-effect signal left doubt that the two results were connected.

Finally, since the late 1990s various experiments with time-resolved reflectivity in different cuprates have reported signals setting in near T* and increasing in strength as the temperature drops, until interrupted by the onset of a separate signal below Tc. The probe is complex and there was a lack of corroborating evidence for the same cuprates; the results did not receive wide attention.

Now the three experimental approaches have all been applied to the same material. All yielded consistent results and all point to the same conclusion: there is a phase transition at the pseudogap phase boundary – the three techniques put it precisely at T*. The electronic states dominating the pseudogap phase do not include Cooper pairs, but nevertheless intrude into the lower-lying superconducting phase and directly influence the motion of Cooper pairs in a way previously overlooked.

"Instead of pairing up, the electrons in the pseudogap phase organize themselves in some very different way," says He. "We currently don't know what exactly it is, and we don't know whether it helps superconductivity or hurts it. But we know the direction to take to move forward."

Says Orenstein, "Coming to grips with a new picture is a little like trying to steer the Titanic, but the fact that all three of these techniques point in the same direction adds to the mounting evidence for the phase change."

Hussain says the critical factor was bringing the Stanford and Berkeley scientists together. "We joined forces to tackle a more complex problem than any of us had tried on our own."

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1.3 / 5 (15) Mar 24, 2011
I believe the secret to high tempertature superconductivity will tie into the secret of dark matter and energy, ultimately revealing the nature of reality.
4.7 / 5 (15) Mar 24, 2011
I believe the secret to high tempertature superconductivity will tie into the secret of dark matter and energy, ultimately revealing the nature of reality.

lol, most likely not
1.8 / 5 (10) Mar 24, 2011
The explanation of HTc superconductivity is quite simple: electrons are stressed mutually within superconductor lattice, so that their repulsive forces overlap heavily and the electrons are gliding along each other without friction. These electrons are compressed with their attraction to the positively charged atoms like hens fighting for tight place around small feeder. Pseudogap state is the situation, when the areas of movable electrons doesn't form the continuous phase - so that that only isolated islands of superconductive electron fluid are formed around holes: the material exhibits most signs of superconductivity without the most important one - the low resistance.
1.8 / 5 (10) Mar 24, 2011
Surprisingly the same explanation can be applied even to low-temperature superconductivity. Many transition metals are known for their high temperature of superconducive transition, whereas just the well conductive alkali metals cannot be made superconductive even at the extremely low temperature. Why is it so? Well, the atoms of transitive metals are held together with their elongated f- and d- orbitals into cage, which are exerting the pressure into electrons inside of smaller and spherical s- orbitals. Inside of alkali metals these binding orbitals aren't present, so that these metals are soft and their electrons cannot be compressed mutually.

And why so big difference between low and high temperature superconductors exists? Well, the binding force of individual orbitals can be never such intensive, like the binding force of the whole atom lattice. Inside of HTc superconductors the electrons are compressed with more atoms at the same moment.
1.4 / 5 (9) Mar 24, 2011
I believe the secret to high temperature superconductivity will tie into the secret of dark matter and energy
IMO superconductivity is nearly classical effect from certain perspective - it just requires to compress electrons sufficiently. We actually know about superconductivity at room temperature outside of material, as J.F.Prins revealed before years. Unfortunately his finding was ignored with mainstream physics in the same way, like the antigravity, cold fusion another findings, because it really doesn't play with classical theory, based on the Cooper pairs formation. Now we can read clearly, "in this particular copper-based superconductor, many of the electrons in the material dont pair off". Such claim was downvoted many time with various trolls here.
3 / 5 (2) Mar 24, 2011
lol yeah where he get that from?
4.6 / 5 (9) Mar 24, 2011
Beelize54: you might consider reading more then the headline and caption before sounding off. This research distinctly disproves your hypothesis that the pseudo-gap is a transition into superconductivity. It is in fact a completely separate phenomenon.
5 / 5 (6) Mar 24, 2011
Instead of pairing up, the electrons in the pseudogap phase organize themselves in some very different way

The electronic states dominating the pseudogap phase do not include Cooper pairs, but nevertheless intrude into the lower-lying superconducting phase and directly influence the motion of Cooper pairs in a way previously overlooked.

and your quote is taken directly out of context, this material does indeed have electrons pairing off into cooper pairs, just not in pseudo-gap.
not rated yet Mar 25, 2011
Sarcasm from sorq?
not rated yet Mar 25, 2011
hi, what dimensions are we talking here? i'd like to see some nano-superconductor pipe arrays perhaps
Mar 25, 2011
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Mar 25, 2011
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Mar 25, 2011
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Mar 25, 2011
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not rated yet Mar 25, 2011
Is this an effect of the material itself, or of the *arrangement* of the material? I am reminded of how, metaphorically, when coding HTML, gaps in the display of items that should be directly adjacent can appear separated by a space due to various minor coding inconsistencies...the code is technically correct, but the order of its interpretation introduces an invisible artifact. (This is an idea I can't state without resorting to metaphor, not a troll.)
1 / 5 (2) Mar 26, 2011
an invisible artifact

not rated yet Mar 26, 2011
Is this an effect of the material itself, or of the *arrangement* of the material?
Only the change in arrangement of subtle part of its electrons - the rest of atoms remains at their places and this change is highly reversible. It's somehow surprising for me, that so deep and pronounced change in conductivity of material doesn't manifest with its mechanical or optical properties in visible way. You'll need rather expensive devices for the detection of the superconductive transition from outside.
not rated yet Mar 27, 2011
I hope it is a new phase of matter. If there's one new phase who knows how many others there may be and what new physics can be learned from them.

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