Affordable Fuel Cells May Get Boost From Artificial Diamonds

Apr 27, 2010
Affordable Fuel Cells May Get Boost From Artificial Diamonds
Oxygen (red spheres) migrates from one vacancy to another inside the scandia-doped cubic zirconia. The cations the oxygen must brush past are marked by the letter E.

(PhysOrg.com) -- Using specialized cubic zirconia or artificial diamonds, scientists from Nanjing Normal University in China and Pacific Northwest National Laboratory designed a membrane that could allow solid oxide fuel cells to operate at lower temperatures and reduce our dependence on fossil fuels. This new membrane, created by adding scandium to cubic zirconia, passes oxygen faster and at temperatures far lower than the more common yttria-stabilized zirconia.

Affordable fuel cells could reduce the need for imported oil. However, solid oxide fuel cells currently don't fit the budget of most homeowners. The cost is tied to the internal temperature of the cell, around 1000 degrees Celsius. This temperature means the cell must be built using very durable, very expensive ceramics. Lower temperatures mean the cells could be built from stainless steel and other less expensive materials. The trick to dropping the temperature, and thus the cost, is the membrane or solid electrolyte that quickly passes oxygen from one side of the cell to the other.

In this study, the team investigated why some materials are better than others at passing oxygen along. "We could take an Edisonian approach—trying 10,000 materials, but it would be expensive, and we'd be here forever," said Dr. Ram Devanathan, a materials scientist at PNNL. "So, we are using all of the tools we have in EMSL—experimental, computational, and theoretical—to look into the materials."

Using oxygen-plasma-assisted molecular beam epitaxy, the researchers grew scandia-stabilized zirconia films on substrates. The films were examined using , electron spectroscopy, and microscopy.

However, experimental data alone was not enough, Devanathan explained. Imagine taking photos at the beginning and end of a raucous party. The photos, like the experiments, show you where you began and where you ended. However, theory shows what happened and why. Theory also allows predictions about what will happen next and what would happen under different circumstances.

So, the team applied theoretical calculations and models to the experimental data. They determined that the nanoscale, nanosecond interactions occurring in the scandia-doped cubic film conducted oxygen faster than the yttrium doping in current electrolytes.

This study provides a fundamental understanding of how ions move in scandia-doped zirconia, and shows the material is very stable. "Our integrated approach takes the science to the next level," said Dr. Theva Thevuthasan, who worked on the project and currently oversees the deposition and microfabrication capability at EMSL.

The scientists are using resources at EMSL and PNNL to provide a more detailed understanding of the atomic interactions in another promising material for fuel cells: nano layers of zirconia and ceria.

Explore further: Global scientific team 'visualizes' a new crystallization process (w/ video)

More information: Yu Z, R Devanathan, W Jiang, P Nachimuthu, V Shutthanandan, LV Saraf, CM Wang, SVNT Kuchibhatla, and S Thevuthasan. 2010. "Integrated Experimental and Modeling Study of Ionic Conductivity of Scandia-Stabilized Zirconia Thin Films." Solid State Ionics 181(8-10):367-371.

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User comments : 5

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Sonhouse
not rated yet Apr 27, 2010
Nice work. What is the new lower temperature? The article does not specify that number.
SongDog
not rated yet Apr 27, 2010
Depends on choice of formulation, but in the 500-900 C range. See http://linkinghub...10000378
Shootist
1 / 5 (1) Apr 27, 2010
Diamonds and platinum. Yep, a great place to start for affordability.
darkhorse
not rated yet Apr 27, 2010
Read the article again, Shootist. The material shares the crystal structure of cubic zirconia (fake diamonds). SOFC's don't require platinum, either. Keep your potshots for topics you understand.
gunslingor1
not rated yet May 03, 2010
ENOUGH RESEARCH ALREADY! WE HAVE PERFECTLY GOOD SOLUTIONS ALREADY!

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