A light touch: Iron complexes as efficient catalysts for the light-driven extraction of hydrogen from water

Dec 02, 2009

(PhysOrg.com) -- Hydrogen is a promising alternative energy carrier that can be efficiently converted into electrical energy in fuel cells. One hurdle to the introduction of sustainable hydrogen technology is the fact that the large-scale industrial production of hydrogen through reforming processes is still largely based on fossil fuels, and thus is not carbon neutral.

"One of the most important goals for chemists is to use solar energy for the generation of energy carriers like hydrogen," says Matthias Beller of the Leibniz Institute for Catalysis in Rostock (Germany). “The biggest attraction is the use of as a source of hydrogen.” Beller’s Rostock team, in collaboration with scientists in Rennes (France), has now developed a new catalytic system that can make this dream come true. As the researchers report in the journal Angewandte Chemie, their efficient system is based on simple, inexpensive iron carbonyl complexes.

By means of photosynthesis, plants are particularly good at converting light into . Their success relies on complicated reaction cascades that are activated by . Electrons are passed on through multiple reaction steps that involve a number of “helper agents”. Based on this principle, light-driven reaction cascades for the reduction of water to hydrogen are currently being developed around the world.

The significant components for Beller’s novel cascade are a photosensitizer, a source of electrons (electron donor), and the actual water-reduction catalyst. The photosensitizer absorbs the incoming light, capturing its . Subsequently, the electron donor transfers an electron to the excited photosensitizer. Now negatively charged, the photosensitizer transfers its extra electron to the water reduction catalyst. The catalyst uses the electron to reduce protons (H+ ions) from the water to hydrogen (H2).

In order for the whole process to proceed, the individual components must be well tuned to each other. The team selected a known photosensitizer that contains the metal iridium; their electron donor is triethylamine. Whereas most researchers have concentrated on expensive precious metals as water reduction catalysts, the Rostock research team settled on an affordable alternative: simple, readily available iron carbonyls (coordination complexes made of iron atoms and CO molecules).

“Our new catalytic system demonstrates that simple and affordable iron complexes can be used for the production of hydrogen from water,” says Beller. “In order to carry out this reaction on a larger scale in the future, we are currently working on improvements to the photosensitizer and the use of water as the electron donor.”

More information: Matthias Beller, Light-Driven Generation: Efficient Iron-Based Water Reduction Catalysts, Angewandte Chemie International Edition, doi: 10.1002/anie.200905115

Provided by Wiley (news : web)

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not rated yet Dec 02, 2009
Just as platinum is used as a solid catalyst for hydrocarbon reformation, magnetic fields could displace ferrous water effectively enough to tear molecules apart.
5 / 5 (1) Dec 02, 2009
Gack! Hydrogen is a trendy idea pushed by business and people who want to sell the outlandishly expensive equipment and infrastructure to support it.

Hydrogen is inefficient to produce, electricity from wind and solar would be better used directly in the power grid instead to replace coal and gas fired energy plants.

It requires mega expensive new infrastructure to replace current hydrocarbon transportation, it is corrosive and requires high pressure systems that require technical expertise that will put all the current mechanics out of their jobs. Sustainable bio-fuel sources that do not compete with food (like waste depolymerization and alage) would reuse our current infrastructure.

Plus it is impossible to fully contain so as it's use grows so will hydrogen leaks, hydrogen rises to the high atmosphere where it reacts to deplete ozone and form water vapor in the normaly dry upper atmosphere where it is a greenhouse gas hundreds of times more potent as CO2.
not rated yet Dec 02, 2009
Hydrogen is inefficient to produce, electricity from wind and solar would be better used directly in the power grid instead to replace coal and gas fired energy plants.

Some applications require a portable fuel (transportation by land, sea and air) that cannot be supplied by electricity (bateries/capacitors). Sooner or later we will need to get away from hydrocarbons - and hydrogen is the cleanest way to do this.