Researchers first to create a single-molecule diode

May 25, 2015
An illustration of the molecule used by Columbia Engineering professor Latha Venkataraman to create the first single-molecule diode with a non-trivial rectification ratio overlaid on the raw current versus voltage data. Diodes are fundamental building blocks of integrated circuits; they allow current to flow in only one direction. Credit: Latha Venkataraman, Columbia Engineering

Under the direction of Latha Venkataraman, associate professor of applied physics at Columbia Engineering, researchers have designed a new technique to create a single-molecule diode, and, in doing so, they have developed molecular diodes that perform 50 times better than all prior designs. Venkataraman's group is the first to develop a single-molecule diode that may have real-world technological applications for nanoscale devices. Their paper, "Single-Molecule Diodes with High On-Off Ratios through Environmental Control," is published May 25 in Nature Nanotechnology.

"Our new approach created a single-molecule diode that has a high (>250) rectification and a high "on" current (~ 0.1 micro Amps)," says Venkataraman. "Constructing a device where the active elements are only a single molecule has long been a tantalizing dream in nanoscience. This goal, which has been the 'holy grail' of molecular electronics ever since its inception with Aviram and Ratner's 1974 seminal paper, represents the ultimate in functional miniaturization that can be achieved for an electronic device."

With electronic devices becoming smaller every day, the field of has become ever more critical in solving the problem of further miniaturization, and single molecules represent the limit of miniaturization. The idea of creating a single-molecule diode was suggested by Arieh Aviram and Mark Ratner who theorized in 1974 that a molecule could act as a rectifier, a one-way conductor of electric current. Researchers have since been exploring the charge-transport properties of molecules. They have shown that single-molecules attached to metal electrodes (single-molecule junctions) can be made to act as a variety of circuit elements, including resistors, switches, transistors, and, indeed, diodes. They have learned that it is possible to see quantum mechanical effects, such as interference, manifest in the conductance properties of molecular junctions.

Since a diode acts as an electricity valve, its structure needs to be asymmetric so that electricity flowing in one direction experiences a different environment than electricity flowing in the other direction. In order to develop a single-molecule diode, researchers have simply designed molecules that have asymmetric structures.

"While such asymmetric molecules do indeed display some diode-like properties, they are not effective," explains Brian Capozzi, a PhD student working with Venkataraman and lead author of the paper. "A well-designed should only allow current to flow in one direction—the 'on' direction—and it should allow a lot of current to flow in that direction. Asymmetric molecular designs have typically suffered from very low current flow in both 'on' and 'off' directions, and the ratio of current flow in the two has typically been low. Ideally, the ratio of 'on' current to 'off' current, the rectification ratio, should be very high."

In order to overcome the issues associated with asymmetric molecular design, Venkataraman and her colleagues—Chemistry Assistant Professor Luis Campos' group at Columbia and Jeffrey Neaton's group at the Molecular Foundry at UC Berkeley—focused on developing an asymmetry in the environment around the molecular junction. They created an environmental asymmetry through a rather simple method—they surrounded the active molecule with an ionic solution and used gold metal electrodes of different sizes to contact the molecule.

Their results achieved rectification ratios as high as 250: 50 times higher than earlier designs. The "on" current flow in their devices can be more than 0.1 microamps, which, Venkataraman notes, is a lot of current to be passing through a single-molecule. And, because this new technique is so easily implemented, it can be applied to all of all types, including those that are made with graphene electrodes.

"It's amazing to be able to design a molecular circuit, using concepts from chemistry and physics, and have it do something functional," Venkataraman says. "The length scale is so small that quantum mechanical effects are absolutely a crucial aspect of the device. So it is truly a triumph to be able to create something that you will never be able to physically see and that behaves as intended."

She and her team are now working on understanding the fundamental physics behind their discovery, and trying to increase the rectification ratios they observed, using new molecular systems.

Explore further: Electronics play by a new set of rules at the molecular scale

More information: Single-molecule diodes with high rectification ratios through environmental control, Nature Nanotechnology, DOI: 10.1038/nnano.2015.97

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not rated yet May 25, 2015
I hate to say it, but the work is actually relevant..even good. Nice that they have achieved high degree of rectification. The RC-constant of the diode should be fantastic..
Whydening Gyre
4.5 / 5 (2) May 25, 2015
Why would you hate to say it...?
not rated yet May 25, 2015
for the lay person, how would it be used?
not rated yet May 25, 2015
I hate to say it, but the work is actually relevant..even good. Nice that they have achieved high degree of rectification. The RC-constant of the diode should be fantastic..

It SHOULD be, but you can't tell from this article if it actually is. It also doesn't say much about forward voltage drop, thermal characteristics, flicker noise, and many other things we design diodes for.

I agree this work ought to be a game changer, but clearly the person who wrote this has never read a specification sheet for a diode.
not rated yet May 26, 2015
"Quantum Mechanical Effects" have little to do with it. This is an electromagnetic effect.
not rated yet May 27, 2015
Electromagnetism is also quantized. Electromagnetism is energetic waves and photons are its quantum units. Interference -- quantum or larger scale -- is a wave mechanical phenomenon. Interacting waves causally interact with and "interfere" with each other, with the interaction amplifying, reducing/distorting, or annihilating each of the interacting waveforms. Electricity, an electric current, is not a flow of physical electrons. It is a flow of electromagnetic wave energy. When a free photon interacts with an atomic electron the energy wave excites the electron into a higher energy orbital. The atom can "carry" the photon of energy in the atom's excited state. If the photon keeps moving out of the atom, it drops the electron back down to its former state. If a long series of atoms are magnetically bound to each other in a wire, photons can pass from atom to atom and the series of em waves flows along the wire using the electrons as its medium.

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