Graphene gives up more of its secrets

Jul 15, 2011
Undoped graphene isn't a metal, semiconductor, or insulator but a semimetal, whose unusual properties include electron-electron interactions between particles widely separated on graphene's honeycomb lattice -- here suggested by an artist's impression of the Feynman diagrams often used to keep track of such interactions. Interactions occur over only very short distances in ordinary metals. Long-range interaction alter the fundamental character of charge carriers in graphene. Credit: Image by Caitlin Youngquist, Lawrence Berkeley National Laboratory

Graphene, a sheet of carbon only a single atom thick, was an object of theoretical speculation long before it was actually made. Theory predicts extraordinary properties for graphene, but testing the predictions against experimental results is often challenging.

Now researchers using the Advanced (ALS) at the U.S. Department of Energy's Lawrence Berkeley National Laboratory (Berkeley Lab) have taken an important step toward confirming that graphene is every bit as unusual as expected – perhaps even more so.

"Graphene is not a semiconductor, not an insulator, and not a metal," says David Siegel, the lead author of a paper in the Proceedings of the National Academy of Sciences (PNAS) reporting the research team's results. "It's a special kind of semimetal, with electronic properties that are even more interesting than one might suspect at first glance."

Siegel is a graduate student in Berkeley Lab's Materials Sciences Division (MSD) and a member of Alessandra Lanzara's group in the Department of Physics at the University of California at Berkeley. He and his colleagues used ALS beamline 12.0.1 to probe a specially prepared sample of graphene with ARPES (angle-resolved photoemission spectroscopy) in order to observe how undoped graphene – the intrinsic material with no extra charge carriers – behaves near the so-called "Dirac point."

Dirac cones of graphene are often drawn with straight sides (left) indicating a smooth increase in energy, but an ARPES spectrum near the Dirac point of undoped graphene (sketched in red at right) exhibits a distinct inward curvature, indicating electronic interactions occurring at increasingly longer range and leading to greater electron velocities -- one of the ways the electronics of semi-metallic graphene differ from a metal's. Credit: Lawrence Berkeley National Laboratory

The Dirac point is a unique feature of graphene's band structure. Unlike the band structure of semiconductors, for example, graphene has no band gap – no gap in energy between the electron-filled valence band and the unoccupied conduction band. In graphene these bands are represented by two cones ("Dirac cones") whose points touch, crossing linearly at the Dirac point. When the valence band of graphene is completely filled and the conduction band is completely empty, the graphene can be considered "undoped" or "charge neutral," and it is here that some of the interesting properties of graphene may be observed.

An ARPES experiment neatly measures a slice through the cones by directly plotting the kinetic energy and angle of electrons that fly out of the graphene sample when they are excited by an x-ray beam from the ALS. A spectrum develops as these emitted electrons hit the detector screen, gradually building up a picture of the cone.

The way the electrons interact in undoped graphene is markedly different from that of a metal: the sides of the cone (or legs of the X, in an ARPES spectrum) develop a distinct inward curvature, indicating that electronic interactions are occurring at increasingly longer range – distances of up to 790 angstroms apart – and lead to greater electron velocities. These are unusual manifestations, never seen before, of a widespread phenomenon called "renormalization."

Experiment versus theory

To understand the significance of the team's findings, it helps to start with their experimental set-up. Ideally, measurements of undoped graphene would be done with a suspended sheet of freestanding graphene. But many experiments can't be done unless the target is resting on a solid substrate, which can influence the electronic properties of the layer on the surface and interfere with the experiment.

So Siegel and his colleagues decided to investigate a special kind of "quasi-freestanding" graphene, starting with a substrate of silicon carbide. When heated, the silicon is driven out of the silicon carbide and carbon gathers on the surface as a relatively thick layer of graphite (the kind of carbon in pencil lead). But adjacent layers of graphene in the thick graphite sample are rotated with respect to one another, so that each layer in the stack behaves like a single isolated layer.

"In solid-state physics one of the most fundamental questions one can ask about a material is the nature of its charge carriers," Siegel says. "For ordinary metals, the answer can be described by the most powerful theory of solids, known as Landau's Fermi-liquid theory," after the Soviet physicist Lev Landau and the Italian and naturalized-American physicist Enrico Fermi.

While individual electrons carry charge – the electric current in a copper wire, for example – even in a metal they can't fully be understood as simple, independent particles. Because they are constantly interacting with other particles, the effects of the interactions have to be included; electrons and interactions together can be thought of as "quasiparticles," which behave much like free electrons but with different masses and velocities. These differences are derived through the mathematical process called renormalization.

Landau's Fermi liquid is made up of quasiparticles. Besides describing features of electrons plus interactions, Fermi liquids have a number of other characteristic properties, and in most materials the theory takes generally the same form. It holds that charge carriers are "dressed" by many-body interactions, which also serve to screen electrons and prevent or reduce their longer-distance interactions.

"Since the properties of so many materials are pretty much the same in a generalized way, physicists are always interested in finding systems that differ from a normal Fermi liquid," says Siegel. "This is what makes our results so exciting. Undoped graphene really does differ from what we expect for a normal Fermi liquid, and our results are in good agreement with theoretical calculations."

Perhaps the most vivid example of the difference is the long-range interaction among electrons in semimetallic graphene, interactions which would be screened in a normal metal. Siegel grants that there may be continuing controversy about how exactly graphene should be expected to behave, "but our main result is that we have confirmed the presence of these unscreened, long-range interactions, which change the behavior of quasiparticles in in a fundamental way."

Explore further: Graphene and diamonds prove a slippery combination

Related Stories

Two graphene layers may be better than one

Apr 27, 2011

( -- Researchers at the National Institute of Standards and Technology have shown that the electronic properties of two layers of graphene vary on the nanometer scale. The surprising new results ...

Toward a better understanding of bilayer graphene

Oct 26, 2010

( -- "Graphene is a very exciting material with a number of interesting possibilities, including for use in electronic devices," Pablo Jarillo-Herrero tells "However, all graphene system ...

Looking for critical behavior in graphene

May 18, 2010

( -- "One of the hopes people have for graphene is in electronic devices. It is seen as a possible replacement for silicon, due to its unique properties," Herb Fertig tells Graphe ...

Turning down the noise in graphene

Aug 06, 2010

( -- Graphene is a two-dimensional crystalline sheet of carbon atoms - meaning it is only one atom thick - through which electrons can race at nearly the speed of light - 100 times faster than ...

Recommended for you

Graphene and diamonds prove a slippery combination

May 25, 2015

Scientists at the U.S. Department of Energy's Argonne National Laboratory have found a way to use tiny diamonds and graphene to give friction the slip, creating a new material combination that demonstrates ...

Artificial muscles get graphene boost

May 22, 2015

Researchers in South Korea have developed an electrode consisting of a single-atom-thick layer of carbon to help make more durable artificial muscles.

How to make continuous rolls of graphene

May 21, 2015

Graphene is a material with a host of potential applications, including in flexible light sources, solar panels that could be integrated into windows, and membranes to desalinate and purify water. But all ...

Carbon nanothreads from compressed benzene

May 20, 2015

A new carbon nanomaterial – the thinnest possible one-dimensional thread that still retains a diamond-like structure – was created by the controlled, slow compression and decompression of benzene. The ...

User comments : 0

Please sign in to add a comment. Registration is free, and takes less than a minute. Read more

Click here to reset your password.
Sign in to get notified via email when new comments are made.