How to free trapped radicals from carboxyl

The removal of carboxyl groups and the release of alkyl radical fragments from the tight binding of carboxyl groups are promising directions in organic synthesis, especially in drug synthesis. Various catalysts have been ...

Chemical hydrogen storage system

Hydrogen is a highly attractive, but also highly explosive energy carrier, which requires safe, lightweight and cheap storage as well as transportation systems. Scientists at the Weizmann Institute of Science, Israel, have ...

Platform optimizes the design of new, tunable catalytic systems

In the late 1700s, a Scottish chemist named Elizabeth Fulhame discovered that certain chemical reactions occurred only in the presence of water and that, at the end of those reactions, the amount of water was not depleted. ...

Cooperative catalysts offer unique route to alkenes

Chemists at Princeton have developed a new chemical method to introduce valuable alkenes into simple hydrocarbon molecules, a transformation known as dehydrogenation, which is found in important processes such as the biosynthesis ...

Taking a cue from nature: Turning alcohols into alkylating agents

Researchers at Princeton have developed a dual catalyst system that directly installs alkyl groups—fragments containing singly bonded carbon and hydrogen atoms that have extremely useful properties for drug discovery—onto ...

New chemistry makes strong bonds weak

Researchers at Princeton have developed a new chemical reaction that breaks the strongest bond in a molecule instead of the weakest, completely reversing the norm for reactions in which bonds are evenly split to form reactive ...

New technique maps twin faces of smallest Janus nanoparticles

(PhysOrg.com) -- New drug delivery systems, solar cells, industrial catalysts and video displays are among the potential applications of special particles that possess two chemically distinct sides. These particles are named ...

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